化学团聚强化除尘协同脱除SO3的研究.docxVIP

化学团聚强化除尘协同脱除SO3的研究 李高磊，赵永椿，张军营* （华中科技大学煤燃烧国家重点实验室，武汉430074） （Tel Email:lgl@hust.edu.cn） 摘 要 本文针对340MW燃煤电厂化学团聚强化除尘技术改造机组，进行了颗粒物及SO3排放控制试验研究。探究了化学团聚强化除尘技术对颗粒物及SO3脱除的促进作用，并分析了化学团聚强化除尘技术协同脱除SO3的机理。试验结果表明：喷入化学团聚剂后，ESP后颗粒物平均浓度和WFGD后颗粒物平均浓度分别降低了约52%和44.7%，机组颗粒物年平均排放浓度约为3.7mg/m3；ESP后SO3脱除效率由41.7%~62.3%提高至63.8%~75.2%，在中低负荷时，提升效果显著，结合WFGD装置，该机组SO3脱除效率为88.2%~92.7%，不同负荷下排放浓度为5.7~9.0mg/m3,平均排放浓度为7.6mg/m3。部分SO3吸附在颗粒物上脱除，验证了化学团聚强化除尘协同脱除SO3的可行性。 关键词 SO3；细颗粒物；化学团聚；超低排放；燃煤电厂 Research on SO3 Removal Accompanied with Improving Particles Removal by Chemical Agglomeration LI Gao-Lei ZHAO Yong-Chun ZHANG Jun-Ying ZHENG Chu-Guang (State Key Laboratory of Coal Combustion, Huazhong University of Science and Technology, Wuhan 430074, China)基金项目 基金项目：国家重点研发计划项目 (2016YFB0600604) 通信作者：张军营，教授，jyzhang@hust.edu.cn Abstract: The emission of particles and SO3 is investigated in 340 Mega Watt coal-fired power plant that was improved by chemical agglomeration technology . It explored the effcet on particles and SO3 removal by chemical agglomeration and revealed the mechanism of improving the SO3 removal efficiency . The results show that the average concentration of particles reduce about 52% and 44.7% in the outlet of ESP and WFGD . The average emission concemtration of particles is about 3.7mg/m3 . The SO3 removal efficiency is improved from 41.7%~62.3% to 63.8%~75.2% in the outlet of ESP . Especially , it is more obvious in middle and low load . The total SO3 removal efficiency is 88.2%~92.7% . The emission concemtration of SO3 is 5.7~9.0mg/m3 in different load , and the average is 7.6mg/m3 . The results show that some SO3 is attached to particles , which proves the feasibility of SO3 removal accompanied with improving particles removal by chemical agglomeration . Key words: SO3; fine particles; chemical agglomeration ; ultra-low emission ; coal-fired power plant 0 引言 据统计，2016年我国火力发电由2015年的下降2.6%转为增长3.5%。火力发电会产生多种污染物，如颗粒物、SOx、NOx、Hg及其化合物等[1]。国务院要求在2020年前，对我国燃煤电厂全面实施超低排放改造。可吸入颗粒物与