不同处理方法对硅灰稳固化垃圾焚烧飞灰重金属的影响.PDFVIP

中国环境科学 2018,38(11) ：4198~4204 China Environmental Science 不同处理方法对硅灰稳固化垃圾焚烧飞灰重金属的影响 * 李军辉,吴 新 ,刘道洁,王 开 (东南大学,能源热转换及其过程测控教育部重点实验室,江 南京 210096) 摘要：向飞灰中添加硅灰与一定比例的去离子水,混合均匀后分别进行自然养护、蒸汽养护和中温热处理.研究了自然养护和蒸汽养护条件下硅灰不同 添加量对垃圾焚烧飞灰浸出毒性的影响,考察了蒸汽养护样与中温热处理样的重金属化学形态分布、晶体结构和微观形貌变化.结果表明: 自然养护和 蒸汽养护条件下,随着硅灰添加量由 0%升至 10%,飞灰中 Pb Cd Cr 和 Cu 的浸出浓度均随之降低. 硅灰添加量为 10%时,硅灰蒸汽养护样中 Pb Cd Cr 和 Cu 的浸出浓度略低于硅灰自然养护样,金属化学形态分布相比原灰变化较小;硅灰中温热处理对飞灰中 Pb Cd Cu 和 Zn 处理最为彻底,4 种金 属残渣态占比相比原灰分别从原灰的37.12% 11.82% 44.30%和51.94%升高至84.75% 75.49% 77.20%和67.40%,酸溶态分别由原灰的3.99% 54.92% 6.56%和 10.49%降低至 0.44% 9.37% 2.72%和 3.59%. 关键词：垃圾焚烧飞灰；硅灰；重金属；中温热处理；蒸汽养护 中图分类号：X705 文献标识码：A 文章编号：1000-6923(2018)11-4198-07 Effects of different treatment methods on the stabilization of heavy metals in municipal solid waste incineration fly ash using silica * fume. LI Jun-hui, WU Xin , LIU Dao-jie, WANG Kai (Key Laboratory of Energy Thermal Conversion and Process Control of Ministry of Education, Southeast University, Nanjing 210096, China). China Environmental Science, 2018,38(11)：4198~4204 Abstract ：After mixing municipal solid waste incineration fly ash (MSWIFA) with silica fume and a certain proportion of deionized water, natural curing, steam curing and thermal treatment were performed respectively to stabilize heavy metals. The effects of additive amounts of silica fume on the leaching of critical heavy metals in MSWIFA with natural curing and steam curing were studied. Specification distribution of heavy metals, crystal structures and microstructures of steam curing samples and thermal treatment samples were also investigated. The results showed