耐高温环氧树脂的合成工艺研究.docVIP

耐高温环氧树脂的合成工艺研究 毕业论文开题报告 题目 耐高温环氧树脂的合成工艺研究 院 系 化工与环境工程学院 专业 高分子材料与工程 年级 2010级 学号 1XXXXXXXXXX 姓名 李胜鹏 指导教师 齐明华 2012 年 03 月 09 日 毕业设计说明书论文中文摘要 环氧树脂是一种重要的热固性树脂因其具有良好的综合性能和工艺性而在复合材料胶黏剂和涂料行业中有着不可代替的作用然而其固化物脆性大耐热性差难以满足日益发展的工程技术要求限制了环氧树脂进一步应用随着高新技术的不断发展对环氧树脂提出了越来越高的要求因而也就不断推动着高性能环氧树脂的研究开发 本论文研究的三酚基甲烷缩水甘油醚是一种耐高温环氧树脂具有良好的韧性和加工性能广泛用于高性能复合材料封装材料等领域本文以苯酚和对羟基苯甲醛为原料合成三酚基甲烷再以三酚基甲烷与环氧氯丙烷 ECH 缩合制备三酚基甲烷缩水甘油醚通过不同条件的对比得出制备三酚基甲烷缩水甘油醚的最佳工艺酰亚胺得到具有良好机械性能和粘强度的耐高温环氧胶黏剂 实验研究合成出了单体三酚基甲烷以及三酚基甲烷缩水甘油醚并采用TIRHPLCNMR对TPM单体环氧树脂的基本性能进行了研究同时创新性的发现并采用二氯甲烷和乙醇溶液来提纯TPM单体结果表明该环氧值为0551HPLC图表明单体纯度是9898 毕业设计说明书论文外文摘要 Title Studies of Synthetic Techniques of Tri 4-hydroxyphe nyl Methane Glycidyl Ether with Phenol and Parahydroxy Benzaldehyde Abstract Epoxy resin is an important thermosetting resin As we known that epoxy resins were widely used as adhesives and matrix resin in composites However most thermosetting resin for many disadvantages such as the great brittleness in the cured state and low heat-resistance so its difficult to fit for the requirements of the developing engineering technology and restricts its application in some special occasion The article introduces tri 4-hydroxyphenyl methane ether is a high temperature resistant epoxy resin It has excellent tenacity and process ability and it is widely used as high performance composite and encapsulation materials The article mainly studies the syntheses of tri 4-hydroxyphenyl methane with phenol and parahydroxy benzaldehyde tri 4-hydroxyphenyl methane glycidyl ether with the tri 4-hydroxyphenyl methane and chloropropane Comparing the diffirent condition of the reaction the optimum synthetic techniques of superior quatily of tri 4-hydroxyphenyl methane glycidyl ether is givenHigh temperature resistant epoxy adhesives had been proved to have good mechanical properties and bonding strength because they combined the advantages of epoxy resin and polyimide resin by m