二维纳米材料基复合催化剂的制备及性能研究-高分子化学身与物理专业毕业论文.docxVIP

AbstractAbstract Abstract Abstract With the decreasing fossil resources and worsening of environment，utilization of solar energy and transforming harmful substance into useful resource are both good solutions，meanwhile，the catalysts play an important role in the above-mentioned ways．Development and utilization of the catalyst has attracted many countries’ attention．In the last decade，the rapid development of two-dimensional materials(2D) creates an opportunity for obtaining catalysts with high activity．The 2D components greatly improve catalytic activities of the hybrid nanocatalysts owning to their unique structure．So far,the insufficient studies on synthetic techniques，structure designs and catalytic mechanism researches have greatly limited application and development of 2D nanocatalysts．The present thesis attempts to obtain high·activity hybrid catalysts based 2D substances with simple and high-efficiency construction methods．Main works are presented as follows： Firstly,the CdS／RGO nanocomposite was successfully synthesized by a reflux condensation method in water．DM匝mixed solution．DⅣ匝Was used as both solvent and reducing agent．The effect of RGO content in CdS／RGO nanocomposites on the photocatalytic degradation of Rhodamine B(RhB)was investigated．RGO was replaced with GO in nanocomposite SO as to investigate what a role conductivity played in photocatalytic process．The selectivity of the catalyst was studied by changing the substrate types．In the end，the mechanism of the improvement of photocatalytic activity of CdS anchored on RGO under solar irradiation was suggested and testified．The results showed that the optimum content of RGO to CdS was 5％while the photocatalytic activity of CdS／RGO nanocomposite was about 300％times higher than that of pure CdS．Conductivity of RGO in nanocomposite played an important role in photocatalytic process．A higher photocatalytic degradation rate was achieved for RhB compared to MB and MO．The mechanism of the improved photocataly