高硅zsm-5沸石分子筛负载纳米零价铁去除水溶液中重金属说机理的研究.docxVIP

ABSTRACTWith ABSTRACT With the development of industry,a large amount of lead and its compounds are widely used in mining，electroplating industry,battery manufacturing,dyes，printing industry and SO on．Lead waste discharged into water,has caused serious pollution of water and great threat human health．In recent years，nano zero-valent iron has been widely used in the removal of lead water．However’nano scale zero-valent iron Was easily oxidized and easy to agglomerate in air．So we prepared nano zero—valent iron loaded on ZSM一5 by chemical impregnation and mall milling methods in order to solve the poor dispersion of nano valent iron and low reactivity problems．Under different conditions，we discuss about the reaction kinetics and mechanism by using two materials to removal of lead．At last we compare the performance with the removal of lead．This research maily to the following contents： We prepare the ZSM一5／ZVI by chemical impregnation and the ball milling methods，the characterization of loaded material showed that nano zero-valent iron particle size in 50nm-lOOnm， spherical structure，uniform size and agglomeration by impregnation method．Iron is homogeneously distributed ZSM-5 by ball milling．0【一Fe is present in the material prepared by two methods Its reaction kinetics analysis show that they are in line with the pseudo--first—。order reaction kinetics when we investigate effects ofdifferent conditions in the solution ofPb2+,and then we fmd that it is not conducive to the removal of Pb2+in the high pH and low pH values．But the removal rate of Pb2+ reached at 41．1％at the pH=4．The removal rates ofPb2+is increased with the increasing ofadditive quantity． The reaction rate constant is consistent with it,the removal rates of Pb2+is decreased with the increasing of Pb2+in the ofmaterial dosing quantity．But absolute removing Pb2+volume is increased． To test the total iron released in the process of reaction，we fmd that total iron released is first increased and then decreased．h