论文--丁苯橡胶接枝马来酸酐对白炭黑丁苯橡胶复合材料性能的影响.docVIP

丁苯橡胶接枝马来酸酐对白炭黑/丁苯橡胶复合材料性能的影响 摘要：采用实验室自制的丁苯橡胶接枝马来酸酐（SBR-g-MAH）用作白炭黑/丁苯橡胶（SBR）复合材料的增容剂，研究了SBR-g-MAH的用量对胶料硫化特性以及硫化胶力学性能和动态力学性能的影响。结果表明，SBR-g-MAH用量在0～100份用量范围内，随着SBR-g-MAH量的增加，胶料的焦烧时间（t10）减小，正硫化时间（t90）增加；胶料的最小转矩（ML）和最大转矩（MH）都呈先上升后下降的趋势，在SBR/SBR-g-MAH的比例为50/50时达到最大值；硫化胶的拉伸强度先增大后减小，撕裂强度先增大后趋于平缓再略微减小，均在SBR/SBR-g-MAH的比例为50/50时达到最大值，300%定伸应力和断裂伸长率呈上升趋势；动态力学性能结果和扫描电镜分析（SEM）表明白炭黑在SBR中的分散以及界面结合情况得到了明显改善。 关键词：丁苯橡胶；马来酸酐；接枝；增容作用 Effect of SBR-g-MAH on Properties of Silica/SBR Composites Abstract: The laboratory-made SBR-g-MAH was used as compatibilizing agent in Silica/SBR Composites, the content of SBR-g-MAH on cure characteristics, mechanical properties and dynamic mechanical properties were investigated. The test results showed that, SBR-g-MAH usage within the scope of the dosage of 0~100phr, with increasing the amount of SBR-g-MAH, the scorch time (t10) decreased and optimum cure time (t90) increased. While the minimum torque compound (ML) and maximum torque (MH) were increased at first and then decreased, they reached peak when the ratio of SBR/SBR-g-MAH was 50/50. The tensile strength of vulcanized rubber first increased and then decreased, tear strength increased first and then leveled off, both in the SBR/SBR-g-MAH ratio of 50/50 reached the maximum, 300% modulus and elongation at break of an upward trend. Results of dynamic mechanical properties and scanning electron microscopy (SEM) indicated that silica dispersion in the SBR and interfacial bonding situation has been significantly improved. Keywords: SBR; maleic anhydride; graft; compatibilization 白炭黑用于轮胎胎面胶，具有抗湿滑性好、耐磨性好、滚动阻力低的特点[1-2]。但是，白炭黑为白色粉末状纳米级粒子，具有比表面积大、粒径小、表面能高、粒子间易团聚等特点，在非极性橡胶中很难分散均匀，为了提高白炭黑与SBR的相容性，一般都要添加增容剂或者对其表面进行改性[3-6]。本论文采用自制的SBR-g-MAH作为白炭黑填充SBR的界面相容剂和分散剂，以改善白炭黑的分散性以及SBR胶料的综合性能，研究了SBR-g-MAH用量对白炭黑填充SBR胶料性能的影响，结果说明，SBR-g-MAH能起到一定的增容作用，能改善白炭黑的分散。 1 实验 1.1 主要原材料 SBR 1502，南京创新化工有限公司；SBR-g-MAH，实验室自制；白炭黑、氧化锌、硬脂酸、硫黄等其他配合剂均为橡胶工业常用的原材料。 1.2 基本配方（质量份，下同） SBR/SBR-g-MAH，100～0/0～100（总量为100）；氧化锌，5.0；硬脂酸，1.5；防老剂4010，1.5