共振瑞利散射光谱在食品添加剂分析中地应用.pdf

西南大学硕十学付论文 reaction and havebeen factors studied．Furthermore， analyticalapplications conditions,influencing reaction enhanced betweenRRS the reasonsofRRS andthe mechanism,the relationship spectra and are discussed． absorptionspectra Theresearchcontentsare舔foIlows： }．Determinationof resonance antiagglomerationpotassiumferrocyanideby Rayleighscattering (RRS)method (1)Basictriuminotriphenylmethanedyes-potassiumferroeyanidesystems Innearneutral resonance of media,the Rayleighscattering(RRS)intensitiespotassium basic ferrocyanideK4[Fe(CN)6】ortriaminotriphenylmethanedyessuch鹄ethylviolet(Ev)，crystal violet(CV)，methyIviolet(MV)amvery withbasic toformthreekindsofion-association RRS triaminotriphanylmethanedyes complexes，their intensitiesare enhancedandnewRRS ion-association greatly spectraappear．These complexes RRS arealllocatedatnear havesimilar characteristicsandtheirmaximum spectral wavelengths ale ofEV is 329 theirsensitivities rim,but obviouslydifferent．Amongthem，thesensitivitysystem that enhancementofRRS the ofMV isthelowest．The highest,and system intensit)，A／is tothe RRSmethodcanbe tothe concentration proportional of【Fe(CN)6]4。，SO