八氨苯文档教材基poss交联改性聚氨酯弹性体的制备跟性能.pdfVIP

V01．38No．4 化工新型材料 第38卷增刊 ·92· NEWCHEMICALMATERIALS 2010年4月 八氨苯基POSS交联改性聚氨酯弹性体的制备与性能 田春蓉王建华 卢成渝 梁书恩蔚春蓉孙杰程克梅 (中国工程物理研究院4艺-y-材料研究所，绵阳621900) 摘要 聚氨酯弹性体纳米复合材料，分别采用FT_IR、光学显微镜，动态热机械(DMA)分析以及热重分析 复合材料的拉伸强度增加，扯断伸长率下降，储能模量增加，阻尼因子下降，玻璃化转变温度升高，热分 解速率降低。 关键词 聚氨酯弹性体，多面体低聚倍半硅氧烷(POss)，纳米复合材料，原位聚合，力学性能 and of crosslinked elastomer PreparationperformanceOapPOSS polyurethane Tian Lu ShuenWei Sun Kemei Jianhua Jie ChunrongWang ChengyuLiang Chunrong Cheng of (InstituteofChemicalMaterials，China 621900) AcademyEngineeringPhysics，Mianyang Abstract usedasa to silsesquioxane(OapPOSS)waserosslinkingagent Octaaminophenylpolyhedraloligomerie networks POSS in-situ transforminfrared preparepolyurethanecontainingthroughpolymerization．Fourierspectroscopy mechanical analysis(TGA)wereemployed (FPIR)，opticmicroscopy，dynamicanalysis(DⅣ【A)andthermo-gravimetric tocharacterizethePOS孓reinforced resultsindicatedthat，with contentsof polyurethanesamples．The increasing Oap— modulusand transition of elon— POSS，tensile POSS／PLIE increased，but strength，storageglass temperature composite at indexandthermal ratedecreased． gationbreak，damping decomposing words Key polyurethaneelastomer，POSS，nanocomposite，in-situpolymerization，mechanicalproperty