高铁酸盐溶液氧化直接耐晒黑G的效果及机理.pdfVIP

中国环境科学 2009,29(11) ：1177~1180 China Environmental Science 高铁酸盐溶液氧化直接耐晒黑 G 的效果及机理 张彦平 1,许国仁 2* (1.河北工业大学土木工程学院,天津 300401 ；2.哈尔滨工业大学市政环境工程学院,黑龙江 哈 尔滨 150090) 摘要：研究了高铁酸盐溶液(FS)降解直接耐晒黑 G(DB19)的效果,并采用 UV-Vis 、GC/MS 等方法对降解机理进行了分析.结果表明,FS 对 DB19 的脱色效果较好,pH7.7 时,5min 的脱色率达到 94% 以上,最佳范围为 pH10.7.FS 的最佳投加量为 20mg/L,反应 60min 时,对 DB19 色 度和 COD 的去除率分别为 95%和 60%. FS 对 DB19 废水 TOC 的去除率为 5%,表明染料大分子难以被完全矿化.UV-Vis 扫描、GC/MS 分 析和体系 pH 值的变化结果表明,染料分子的偶氮键能被迅速攻击破坏,使染料消色,染料大分子被氧化为有机小分子中间产物,提高了染料 废水的可生化性, 同时产生大量的酸性有机中间物质,导致体系的 pH 值显著降低. 关键词：高铁酸盐；直接耐晒黑 G ；印染废水；氧化 中图分类号：X703.5 文献标识码 A 文章编号：1000-6923(2009)11-1177-04 1 2* Degradation and mechanism of direct fast black G with ferrate solution. ZHANG Yan-ping , XU Guo-ren (1.School of civil engineering, Hebei University of Technology, Tianjin 300401, China ；2.School of Municipal and Environmental Engineering, Harbin Institute of Technology, Harbin 150090, China). China Environmental Science, 2009,29(11)：1177~1180 Abstract ：The degradation of direct fast black G (DB19) with ferrate solution (FS) was studied, and the mechanism was analyzed by UV-Vis and GC/MS methods. The decolorization ratio was above 94% after 5min in the presence of FS at pH7.7, and the optimal range of pH was lower than 10.7. The decolorization ratio and COD removal ratio were 95% and 60% after 60min, respectively, in the case of FS which dosage was 20mg/L. TOC removal ratio of DB19 was only 5% when ferrate was supplied to reaction system, which indicated that it was difficult for FS to mineralize dye macromolecule. The results of UV-Vis, GC/MS and pH change showed that the azo bonds of dye molecule were attracted and cleaved, causing decolorization of DB19. The dye macromolecule could be oxidized to small molecule, wh