武汉某退役电镀车间场地土壤重金属污染及形态分析.docxVIP

武汉某退役电镀车间场地土壤重金属污染及形态分析 雍正罗泽娇，宋萌萌 冲国地质大学生物地质与环境地质国 家重点实验室 湖北武汉430074) 摘 要：以武汉市某退役电镀车间场地受重金属污染的土壤为研究对象?通过在电镀车间周用采集不同深度的土 壤样品，对土壤中彳种重金属Cu、Ni￡r、Zn的污染特征进行了分析，并采用Tessier五步连续提取法对污染较为典 型的红色黏土中这4种重金属的可交换态碳酸盐结合态、铁镒氧化物结合态市机结合态、残渣态等形态构成进 行了分析。结果表明：调查场地土壤屮超 很》B级标准的逼金属污染物主要杲Zn tu份布在废弃槽堆放区、镀铜 区域吨解镀锌区和危睑废物储地附近，污染深度在土壤农层及表层以下2 m左右但在地面建筑承台、电镀槽附 近污染深度可超过2 m甚至达到4 m Cu r Ni 3种雨金属主耍以铁镭氧化物结合态 有机结合态 锻渣态为主耍 存在形态，占总量的比例分别为90% 98% 95%，Zn主耍以残渣态为主要形态，占总疑的比例为88%。该研究旨 在表征以中更新统冲洪积层红色黏土受重金属污染的空间分布规律及其存在形态特征?以为土壤重金屈污染防治 及其修复提供参考依据。 关键词：土壤；重金属污染；重金属赋存形态：某退役电镀车间场地 中图分类号：X53 文献标识码:A 文章编号：1671—1556 ?014)03-0046-05 Heavy Metal Pollution and Fractional Analysis in the Soil ofa Retired Electroplating Workshop Site YONG Zheng LUO Ze^iao SONG Meng—meng 0 -State Key Laboratory of Biogeology and Environmental Geology China University of Geosciences Wuhan 430074 China) Abstract -This paper investigates the heavily polluted soil from a retired electroplating workshop site in Wuhan. The paper collects soil samples of different depths in the polluted place and analyses the concentra— lio ns of Cu Ni Cr and Zn after HCL—HNOs —HF—HC1O4 digestion and it also analyses the concentrations o f the heavy metal fractions such as exchangeable fraction carbonated fraction Won and manganese oxides combination fraction organic combination fraction and residual fraction by Tessier sequential extraction method? The results show that the main fractions of Cu and Ni are iron and manganese oxides combina— tio n fraction ^organic combination fraction and residual fraction Znd the percentages of the total values arc 9 0% 98% and 95% respectively ；the main fraction of Zn is residual fraction and the percentage of the total value is 88% . The purpose of the study is to characterize the spatial distribution and morphology of heavy me tai pollution in red clay in Q2al + 1 and provide the reference for pollution prevention and soil remedia— tio n? Keywords :soil :heavy metal pollution ；hcavy metal fraction retired electroplating works