聚乙烯蜡超细微乳液的制备及其性能研究.docVIP

聚乙烯蜡超细微乳液的制备及其性能研究 第29卷第2期 2012年2月 印染助剂 TEXTILEAUXIUARIES Vo1.29No.2 Feb.2012 聚乙烯蜡超细微乳液的制备及其性能研究 钟少锋,刘晓云,傅越江,吴幼泉z,王黎明2吴仁妹z,黄小军 (1.浙江工业职业技术学院纺织工程分院,浙江绍兴312000;2.浙江精业生化有限公司,浙江杭州311247; 3.浙江大学高分子科学与工程学系.浙江杭州310027) 摘要:以聚乙烯蜡6100为原料,采用直接高温高压法制备聚乙烯蜡微乳液;系统研究了乳化剂HLB值,乳化剂用量,乳化 时间,乳化温度,pH,搅拌速度等因素对聚乙烯蜡乳液性能的影响,并分别采用场发射透射电子显微镜(FE—TEM)和激光动态光散射仪 (DLS)等研究了乳液微粒形态,粒径及其分布.结果表明,适宜的乳化工艺条件:复合乳化剂的HLB为14.8,复合乳化剂用量为6-4%,乳 化时间为40min,乳化温度为130oC,搅拌速度为60r/min,pH=8.在该条件下可制得固含量高达40%,平均粒径为5Onm,具有良好稳定 性和分散性的聚乙烯蜡超细微乳液,该乳液可以赋予织物柔软丰满的手感,减少织物表面摩擦阻力,显着改善织物的可缝纫性等. 关键词:聚乙烯蜡;微乳液;乳化;乳化剂 中图分类号:TQ630.4文献标识码:B文章编号:1004—0439(2012)02—0032—04 Studyonthepreparationandpropertiesofpolyethylenewax ultrafinemicro..emulsion ZHONGShao-feng,LIUXiao—yun,FUYue-jiang~,唧You—quan2, WANGLi—ming2,IRen-mei2,HUANGXiao-jun~ (1.SchoolofTextile,Zh~iangIndust~Pol~echnicCollege,Shaoxing312000,China;2.ZhejiangJingye Chemamp;Bio.Co.,Ltd.,Hangzhou311247,China;3.DepartmentofPolymerScienceand Engneering,ZhejiangUniversity,Hangzhou310027,China) Abstract:Polyethylenewaxmicro-emulsionwaspreparedfrOmpolyethylenewax61OObyhightempera— tureandhigh-pressuremethodinhermeticconditions.InfluencesofHLBnumberanddosageofemulsifier, emulsificationtime,temperature,pH,stirringspeedandcoolingconditionsonthepropertiesofpolyethylenewax emulsionwereinvestigated.FurthermOre,themorphology,particlesizeanddistributionoftheemulsionwerean— alyzedbyfieldemission-transmissionelectronmicroscope(FE—TEM)andlaserdynamiclightemissiondevice(DLS). Theresultsshowedthattheoptimumemulsificationconditionwas:HLBnumberwas14.8,thedosageofcom— poundemulsifierwas6.4%,andthewaxwasemulsifiedat130oCfor40minwith60r/minofstirringspeedun— derpH8.Thepolyethylenewaxultrafinemicro—emulsionwithmorethan40%ofsolidcontent.50nmofaver— ageparticlesize,goodstabilityanddispersibilitycouldbeobtainedundertheoptimumcondition.Thesoftness andfullnessofthefabrictreatedwiththiskindofultrafinemicro—emulsionwasobviouslyimproved.FrictionaIre— sistanceofthefabricsurfacecouldbereduced,andthetailoringpropertieso