碳_碳化硅复合材料上莫来石涂层的制备及氧化行为.docVIP

碳/碳化硅复合材料上莫来石涂层的制备及氧化行为 姚亚东,温海明,董绍明,郭向利,尹光福 (四川大学材料科学与工程学院,成都 610064 摘 要:以正硅酸乙酯[(C 2H 54SiO 4,ethyl orthosilicate ,TEOS]和硝酸铝[Al(NO 33·9H 2O]为原料,制备了莫来石(3Al 2O 3·2SiO 2,mullite溶胶,用浸涂法在碳/碳化硅(C f /SiC ,下角f 表示纤维,下同上制备3Al 2O 3·2SiO 2涂层(mullite coating, MC。对C f /SiC 和C f /SiC MC 进行了等温–氧化实验,并研究了两者的氧化规律。结果表明:C f /SiC 和C f /SiC MC 的氧化都可以划分为3个主要阶段:θ700 ℃;700 ℃θ1 000 ℃;1 000 ℃θ1 200 ℃。在各个阶段,控制氧化速率的机理各有不同,C f /SiC MC 的氧化质量损失比C f /SiC 的低50%左右,表现出较好的抗氧化性能。 关键词:碳/碳化硅复合材料;莫来石涂层;防氧化;溶胶–凝胶法 中图分类号:TB332 文献标识码:A 文章编号:0454–5648(200703–0322–05 PREPARATION AND ANTI-OXIDATION BEHA VIOR OF MULLITE COATING ON CARBON/SILICON CARBIDE COMPOSITE YAO Yadong ,WEN Haiming ,DONG Shaoming ,GUO Xiangli ,YIN Guangfu (College of Materials Science Engineering, Sichuan University, Chengdu 610064, China Abstract: Ethyl orthosilicate (TEOS and aluminum nitrate were used as raw materials for preparation of mullite sol. The mullite coating (MC on carbon/silicon carbide (C f /SiC, f refers to fiber, the same below was prepared by the dip coating method. Isothermal oxidation tests were performed on C f /SiC and C f /SiC MC and their oxidation behaviors were studied. The results show that the oxida-tion of C f /SiC and C f /SiC MC can be divided into three main stages: θ700 , 700℃ ℃θ1 000 , 1℃ 000 ℃θ1 200 . The oxid ℃a-tion rate-determining steps for each stage are different; the mass loss percentage of the C f /SiC MC was fifty percent lower than that of the C f /SiC. The C f /SiC MC has good oxidation resistance. Key words: carbon/silicon carbide composite; mullite coating; oxidation protection; sol–gel method 碳(C纤维增强碳化硅(SiC复合材料(carbon/ silicon carbide composite, C f /SiC ,下角f 表示纤维,下同具有一系列优异性能,被广泛应用于热端结构部件中。然而,C f /SiC 存在高温氧化的问题,必须对其进行防氧化处理。用耐高温氧化材料在C f /SiC 的表面涂层,阻止氧与C f /SiC 的接触,是一种很有效的提高C f /SiC 抗氧化能力的方法[1]。 目前,制备C f /SiC 防氧化涂层的方法有很多,如:热喷涂(hot spraying、刷涂(brush plating、离子注射(ion planting、物理气相沉积(physical vapor deposition, PVD、物理化学气相沉积(physical chemical vapor deposition, CVD、等离子体喷涂(plasma-spraying等[2–4]。上述方法均有