生物滴滤塔净化苯乙烯废气的实验研究.docVIP

第6卷第2期 环境工程学报 Vol ．6,No ．22012年2月 Chinese Journal of Environmental Engineering Feb．2012 生物滴滤塔净化苯乙烯废气的实验研究 袁青彬 李景义 庞金钊 * (天津科技大学海洋科学与工程学院,天津300457 摘要采用生物滴滤(BTF 系统对含苯乙烯的有机废气进行了生物净化实验并研究该系统VOCs 生物降解性能。 实验表明,苯乙烯进气浓度低于20mg /m 3时BTF 去除效率可达92%以上,出口苯乙烯浓度低于1.6mg /m 3 ,达到GB14554-1993中规定的排放标准;该BTF 装置对苯乙烯的去除负荷在2.0g /(m 3·h 左右;系统稳定运行时循环液COD 、浊度和pH 等都保持稳定,无脱落生物膜积累现象;生物滴滤塔系统适宜的气液比为300;系统总压降约100Pa ,鲍尔环填料和聚氨酯发泡填料混合装填方式可以降低系统压降并有利于微生物挂膜。 关键词 生物滴滤塔 苯乙烯 去除负荷 去除率 中图分类号 X701.7 文献标识码 A 文章编号1673-9108(201202-0589-05Study on purification of gaseous styrene with biotrickling filter Yuan Qingbin Li Jingyi Pang Jinzhao (College of Marine Science and Engineering ,Tianjin University of Science ＆Technology ,Tianjin 300457,China Abstract Some biological purification experiments were carried out by biotrickling filter (BTF system to control air pollution due to volatile organic compounds containing styrene．The results showed that the removal ef-ficiency was over 92%when styrene inlet concentration was below 20mg /m 3．The discharge could meet the standards prescribed by GB14554-1993．And the maximum removal capacity was about 2g /(m 3·h ;COD , turbidity and pH of the circulating culture fluid generally also kept stable while the BTF system was in stable op-eration ;the suitable gas-liquid ratio of the system was about 300and its total pressure drop was about 100Pa etc．All the phenomena indicated that the improvements of filler packing and the microorganism system could greatly optimize the BTF system． Key words biotrickling filter ;styrene ;removal capacity ;removal efficiency 收稿日期:2010－06－29;修订日期:2010－07－27 作者简介:袁青彬(1987 ,男,硕士研究生,主要从事污水处理及 大气污染治理研究工作。E-mail :cctv44996@yahoo．com．cn *通讯联系人,E-mail :jzpang@sina．com 在精细化工、塑料、油漆和涂料生产等诸多领域的生产过程中会产生大量含有挥发性有机化合物(volatile organic compounds ,VOCs 的废气,包括氨气、碳氢化合物、苯及其衍生物、酚及其衍生物、醇 类、醛类、酮类和脂肪酸等 [1,2] 。这些废气会对生态环境和人体健康产生很大危害[3,4] 。为此,各国颁 布了相应的法令,限制该类气体的排放,我国于 1997年颁布并实施的《大气污染综合排放标准》,限 定33种污染物的排放限值,于1994年颁布并实施的《恶臭污染物排放标准》分年限规定了包括苯乙烯在内的8种恶臭污染物的排放限值。 目前常见的处理VOCs 的方法主要有吸