lecture5PLUG FLOW REACTOR化学反应器分析.pptVIP

Example Example c. the maximum value of F Cout =(F tot ) 0 is 0.290, and it is reached at t =1.64. The highest production rate of product C is d. Example Example Select Reactions 1, 2, and 3 as a set of independent reactions We select the feed stream as the reference stream Example Example Example Nonisothermal operations Nonisothermal operations For co-current flow, Nonisothermal operations For countercurrent flow Procedure for setting up the energy balance equation ? 1. Select and define the temperature of the reference stream, T 0 . ? 2. Determine the specific molar heat capacity of the reference stream. ? 3. Determine the dimensionless activation energies of all chemical reactions. ? 4. Determine the dimensionless heat of reactions of the independent reactions. ? 5. Determine the correction factor of the heat capacity of the reacting fluid, ? 6. Specify the dimensionless heat-transfer number, HTN ? 7. Determine (or specify) the inlet temperature. ? 8. Determine (or specify) the inlet dimensionless temperature of the heating/cooling fluid. ? 9. Solve the design equations simultaneously with the energy balance equation, and, if necessary, the energy balance equation of the heating/cooling fluid to obtain Z m s, , and F as functions of the dimensionless space time, t. Solution We select the inlet stream as the reference stream Solution Solution Solution a. The highest value of F V /(F tot ) 0 is 0.147, and it is reached at τ =3.85. b. c. Solution d. For adiabatic operations, HTN =0. PLUG-FLOW REACTOR Review ? Design equations of ideal Batch reactors ? Design equations of ideal CSTR ? Design equations of ideal PFR Plug-flow reactor ? The reactor is operated at steady state. ? The fluid moves in a flat (pistonlike or “plug”) velocity profile. ? There is no spatial variation in species concentrations or temperature at any cross section in the reactor. Tubular reactors, for turbulent flows, L/D 20, for laminar flows, L/D 200. No mixing takes