刚性对羟基化合物的合成-毕业论文.docxVIP

刚性对羟基化合物的合成 摘要 刚性对羟基化合物可作为液晶单体，与环氧树脂反应生成液晶环氧树脂，是合成液晶环氧树脂不可或缺的原材料。具有芳香族刚性棒状部分的聚合物具有优异的热性能和机械性能，也表现出液晶行为。近年来，含刚性棒状结构的环氧树脂被合成为一类新型高性能聚合物。刚性棒状环氧树脂具有液晶行为，它们的环氧环交联能力降低了各向异性。未固化的环氧树脂是单体或低聚物，熔点低，易于加工。液晶环氧树脂（LCER）通过介晶结构之间的π-π相互作用诱导其自发分子取向，从而提高树脂的结晶度。分子取向能通过声子振动实现有效的热传递，因此是决定非晶态和晶体物质导热性的一个关键因素。本文先讲述了液晶环氧树脂的种类和合成方法，以及近年来国内外液晶环氧树脂的合成和研究进展，分析了液晶环氧树脂研究和应用中存在的问题，并对液晶环氧树脂材料的发展方向作出了展望；然后介绍了刚性对羟基化合物，再着重提出了合成三种液晶单体（对羟基苯甲酸对苯二酚酯、4,4-二羟基苯乙酮嗪、二对羟基苯甲酸联苯二酚酯）的方法及表征，为合成综合性能完善的液晶环氧树脂提供原料。 关键词：液晶单体，合成，表征，液晶环氧树脂，发展 SYNTHESIS OF RIGID p-HYDROXYL COMPOUNDS Abstract Rigid p-hydroxy compounds can be used as liquid crystal monomers and react with epoxy resin to produce liquid crystal epoxy resin, which is an indispensable raw material for synthesis of liquid crystal epoxy resin. Polymers with aromatic rigid rods exhibit excellent thermal and mechanical properties and liquid crystal behavior. In recent years, epoxy resin with rigid rod structure has been synthesized as a new type of high performance polymer. Rigid rod-like epoxy resins exhibit liquid crystal behavior, and their epoxy ring crosslinking ability reduces anisotropy. Uncured epoxy resin is monomer or oligomer with low melting point and easy to process. Liquid crystal epoxy resin (LCER) induces spontaneous molecular orientation through the pi-pi interaction between mesomorphic structures, thus improving the crystallinity of the resin. Molecular orientation is a key factor in determining the thermal conductivity of amorphous and crystalline materials because it can achieve effective heat transfer through phonon vibration. In this paper, the types and synthesis methods of liquid crystalline epoxy resins are described, and the synthesis and research progress of liquid crystalline epoxy resins at home and abroad in recent years are described. The problems existing in the research and application of liquid crystalline epoxy resins are analyzed, and the development direction of liquid crystalline epoxy resins is prospected. Then, the rigid p-hyd