NDGA分子印迹材料的制备及性能研究.doc

去甲二氢愈创木酸印迹材料制备及性能研究 摘要：分子印迹技术是将模板分子通过物理或化学反应“烙印”在某种基质上，从而实现聚合物对模板分子的特异性选择的目的。分子印迹聚合物的制备过程中，功能单体、交联剂、溶剂及引发剂的种类和它们的摩尔比对其有影响。根据模板分子的结构或官能团来选择功能单体。分子印迹聚合物的制备通常是应用自由基的聚合反应，交联剂的选择对实验有影响。溶剂的某些性质对印迹反应的发生有很大的影响。 本文以SiO2作为载体， NDGA为模板分子,APTS作为功能单体，TEOS作为交联剂，制备出对NDGA具有特异性识别功能的分子印迹聚合物，然后对其的吸附量以及吸附性能进行探索。 关键词:分子印迹聚合物；NDGA；功能单体；交联剂。 The research of NDGA molecularly imprinted materials preparation conditions and performance Abstract: Molecular imprinting technology is the template molecules are imprinted in a matrix by physical or chemical reaction, so as to realize the specific choice of polymer of template molecules. In the process of the preparation of molecularly imprinted polymers, functional monomer, crosslinking agent, solvent and initiator types and their molar ratio are on the influential. The select of the functional monomer are according to the template molecule structure or functional group. The preparation of molecularly imprinted polymer is usually applied free radical polymerization reaction, the choice of crosslinking agent have influence on experiment. Some properties of solvents for imprinting reaction have a great influence. This paper on SiO2 as the carrier, NDGA as template molecule, APTS as functional monomer, TEOS as crosslinking agent, was prepared to NDGA has specific recognition of the molecularly imprinted polymer, and then to explore its adsorption capacity and adsorption performance. Key words: molecularly imprinted polymer;? NDGA; functional monomer; Crosslinking agent. 目录 TOC \o 1-3 \h \z \u 1 绪论 1 1.1 分子印迹原理 1 1.2 分子印迹法的分类 1 1.2.1 共价法 1 1.2.2 非共价法 2 1.2.3半共价法 2 1.3 制备分子印迹材料的方法 3 1.3.1 本体聚合 3 1.3.2 原位聚合 4 1.3.3 悬浮聚合 4 1.3.4 沉淀聚合 4 1.3.5 表面分子印迹法 5 1.4 制备分子印迹聚合物的影响因素 5 1.4.1 模板分子 6 1.4.2 功能单体 6 1.4.3 交联剂 7 1.4.4 致孔剂 7 1.4.5 引发方式和引发剂的选择 7 1.5分子印迹技术的应用 8 1.5.1 色谱分析 8 1.5.2 固相萃取 8 1.5.3 膜分离技术 9 1.5.4 化学仿生传感器 9 1.6 本课题研究内容意义 9 2.实验部分 11 2.1仪