环氧树脂改性聚氨酯防腐涂料的制备与性能研究.docVIP

环氧树脂改性聚氨酯防腐涂料的制备与性能研究 摘要 本实验以甲苯二异氰酸酯（TDI）和聚乙二醇（PEG）为原料合成聚氨酯预聚体，然后再加入二甲基硅油、环氧树脂、扩链剂、交联剂、增塑剂等,控制反应时间和反应温度,得到有机硅和环氧树脂复合改性的聚氨酯防腐涂料。通过改变TDI和PEG的配比及有机硅、环氧树脂的添加量来研究改性聚氨酯防腐涂料的性能，并得到了适宜的配比和添加量。结明表明，当加入的TDI和PEG的配比值R为2左右，有机硅、环氧树脂的加入分别为8%,7% (均为质量分数),反应温度60℃时可获得性能较好的改聚氨酯涂料,涂膜具有较高的力学强度、良好的存储稳定性和耐酸碱性能。 关键词：聚氨酯涂料;有机硅;环氧树脂;复合改性 Study on the synthesis and properties of polyurethane anti-corrosion paint modified by epoxy resin system Abstract In this experiment, toluene diisocyanate(TDI) and polyethylene glycol(PEG) asraw material composes polyurethane prepolymer, and then adds simethiconeepoxy resin, a chain extender, crosslinking agent, plasticizer etc. By controlling the reaction time and the reaction temperature ,we get the polyurethana coatings which composite modified with the sicicone and epoxy resin. By changing theratio ofTDI and PEG, and the addition agent of the silicone, epoxy resin, plasticizer etc, studythe properties of modified polyurethane anti-corrosion paint, and ensure the best ratio nd adding amount. Conclusion shows , when the addition of TDI and PEG ratio is between 1.8:1 to 2.0:1；increase the amount of silicone, epoxy resin, plasticizer are 8%, 7%, 5%；the reaction temperature is 60℃can get the performance of the modified polyurethane paint, the coating had high water absorption strength, good adhesion, low rate, good thermal stability and resistance to acid and base. Key words:polyurethane coating; organic silicon; epoxy resin; modification 主要符号表 TDI 甲苯二异氰酸酯 PEG 聚乙二醇 R 傅里叶转换红外光谱 R值 -NCO与-OH的摩尔比 目录 TOC \o 1-3 \h \u 6566 摘要 I 19800 Abstract I 16764 主要符号表 II 31026 1 绪论 1 25945 1.1前言 1 30672 1.2 聚氨酯防腐涂料的改性的研究进展与发展趋势 1 14168 1.2.1 研究进展 1 24805 1.2.2 发展趋势 2 1280 1.3 聚氨酯防腐涂料的防腐机理 3 27353 1.3.1涂膜的屏蔽隔离作用 3 25988 1.3.2 涂膜的缓蚀、钝化作用 3 18643 1.3.3 电化学保护作用 3 23845 1.4 聚氨酯防腐涂料的分类 3 31969 1.4.1单组分潮气固化型聚氨酯防腐蚀涂料 3 326 1.4.2湿气直接固化聚氨酯涂料 4 7231 1.4.3烘干型封端聚氨酯涂料 4 6667 1.4.4双组分聚氨酯防腐