262BD的生产工艺和性能检测.docVIP

262BD的生产工艺和性能检测 摘要：本文对不饱和聚酯树脂在玻璃钢制品、浇铸制品、工艺品、木器涂层、纽扣、游艇、摩托汽艇、卫生洁具及其它工业用品中的应用和在低收缩性树脂、阻燃性树脂、强韧性树脂、低挥发性树脂和耐腐蚀性树脂等方面的技术发展进行了综述。确定了松香改性不饱和聚酯树脂的配方及合成工艺，制得了松香改性不饱和聚酯树脂，并进行了酸值、外观、胶凝时间、厚层固化时间和粘度的性能测试。实验结果表明：酸值随时间的增加而减小；凝胶时间随凝胶温度的升高而减少；固化时间随固化温度升高而减少。松香改性不饱和聚酯树脂的配方及合成工艺的研究，为不饱和聚酯的改性提供了探讨方向和实验基础，合成的不饱和聚酯树脂具有较好的性能，为不饱和聚酯树脂的应用提供了更广阔的前景。 关键词：松香；不饱和聚酯树脂；性能测试 Abstract: This article introduces the applications of Unsaturated Polyester Resins to the callings such as glass-steel, casting, crafts and works, carpentry coat, fastener, barge, auto-boat and other industries, the development of technology of low-shrinking resins, burning-preventing, high-toughness resins, low-volatilization resins and cautery-resistance, etc. is introduced too. The craft of rosin modified Unsaturated Polyester Resins is confirmed, rosin modified Unsaturated Polyester Resins is made too, and measured or tested acid value, glue congeals time, thick layer solidification time, adhibit property and aspect of resins .The experimental result indicates that the acid value reduces along with the increasement of time. The glue congeals time increases along with the rising temperature. The time of solidification decreases along with the rising temperature. The craft of rosin modified Unsaturated Polyester Resins provides an accurate direction and experimental basis for the further research. The rosin modified Unsaturated Polyester Resins has favorable performances, which provides a wider applying prospect. Key words: rosin; Unsaturated Polyester Resins; performance testing 目 录 TOC \o 1-3 \h \z 1 前言 1 1.1 不饱和聚酯树脂概述 1 1.1.1 国外UPR发展现状 1 1.1.2 我国UPR树脂发展现状 3 1.2 发展需求 5 2 合成原理与实验 7 2.1 反应机理 7 2.2 实验部分 7 2.2.1 药品与仪器 7 2.2.2 合成 8 2.2.3 性能测试 11 3 实验结果与讨论 13 3.1 反应温度对树脂的影响 13 3.2 反应过程中的酸值 13 3.3 外观和透明度 14 3.4 胶凝时间 15 3.5 粘度 16 3.6 厚层固化时间 16 3.7 苯乙烯对树脂的影响 17 4 结论 19 参考文献 20 致谢 21 1 前言 1.1 不饱和聚酯树脂概述 不饱和聚酯树脂（Unsaturated Polyester Resins,UPR）是由二元酸（包括饱和的及不饱和的）