电镜和透射电镜在聚合物研究中应用.pptVIP

电镜和透射电镜在聚合物研究中应用; 1991年，日本电子公司（NEC）的饭岛澄男博士在用电子显微镜观察石墨电极直流放电的产物时，发现一种新的碳结构——碳纳米管（Carbon Nanotubes, CNTs），自此开辟了碳科学发展的新篇章，也把人们带入了纳米科技的新时代。 ;什么是碳纳米管？;Single-wall nanotubes (left) and Multi-wall nanotubes (right) (from Thomas Swan Company);SEM (a) and TEM (b) microphotographs of MWCNT.;碳纳米管的制备 ;碳纳米管的独特性能;超高的力学性能 ;碳纳米管的应用;Number of journal articles and the issued and pending patents on CNTs and CNT-based polymer composites as a function of year;碳纳米管/聚合物复合材料制备方法;Polyetherimide / CNT (1 wt%) composite prepared by in-situ polymerization.;Optical microscopy images of chitosan（壳聚糖）/MWNTs nanocomposite films containing 0.8 and 2.0 wt % MWNTs.;Melt compounding using twin-screw mixer;碳纳米管/聚合物复合材料;碳纳米管的预处理;Functionalization of MWNTs;Typical TEM image illustrating the graphitic layer structure of a MWNT with curvature and defects on one side of the CNTs at higher magnification.;Preparation and Mechanical Properties of Chitosan/Carbon Nanotubes Composites;Introduction; Preparation of Materials Chitosan of high molecular weight (Mv average molecular weight =182 500 g·mol-1) MWNTs (CVD): Co-Mo/MgO catalysts VH2SO4:VHNO3=1:2 ;2.2 Preparation of the Nanocomposites Films MWNTs+100 mL of distilled water;SEM images showing an overall morphology of a failure surface for chitosan/0.8%MWNTs nanocomposite: (A) low magnification;;TEM image of a thin section of the chitosan/0.8%MWNTs nanocomposite.;Optical microscopy images of chitosan/MWNTs nanocomposite films containing 0.8 and 2.0 wt % MWNTs.; Typical stress-strain curves of neat chitosan and its MWNTs nanocomposite at a crosshead speed of 5 mm/min. (B) Tensile modulus (E) and yield strength of chitosan/MWNTs nanocomposites as a function of MWNTs concentration.;Mechanical Properties of Neat Chitosan and Its MWNTs Nanocomposites ;Conclusions;Melt compounding using twin-screw mixer;A;Tensile Property;Interaction of functionalized CNTs