不同PH条件下方解石对磷的吸附 解吸研究.docVIP

PAGE PAGE 17 不同PH条件下方解石对磷的吸附/解吸研究 摘要：本文主要进行了不同PH条件下方解石对磷的吸附/解吸研究，结果表明：1）动力学曲线表明:PH为7.7，初始磷浓度为5ppm、7.5ppm、10ppm时，吸附量分别在吸附时间达到6h、3h、1.5h后迅速增大，且解吸量减少或无解吸产生，推测在此阶段有沉淀过程发生；PH为8.3，初始磷浓度为10ppm时，在吸附10h后吸附量突然增加，解吸量却减少，推测在此阶段有沉淀发生。2）在温度为25℃ 关键词：方解石；磷；吸附/解吸；动力学 Dsorption / Desorption of phosphorus on calcite under different PH conditions Abstract: In this paper, the adsorption / desorption of phosphorus under different PH conditions was studied. The results showed that：1) kinetic curves show , PH 7.7, initial phosphorus concentration is 5ppm, 7.5ppm, 10 ppm, the adsorption amount respectively in the adsorption time to 6 h, 3 h, 1.5 h after increases rapidly and desorption decreased or no desorption, suggesting that at this stage precipitation process; pH 8.3, initial phosphorus concentration of 10ppm. After 10 h of adsorption adsorption capacity of a sudden increase, desorption is reduced, suggesting that at this stage there is precipitation occurred. 2）Under the same conditions, the removal rate of calcite was decreased with the increase of PH under the same temperature as 25 C and the initial phosphorus concentration. When PH was 7.7, the maximum removal rate was about 95%, the second was PH 8.3, the maximum removal rate was about 85%, Under the condition of PH9.1 and 10.1, the removal rate was the lowest. 3) in PH for 7.7 and 8.3, respectively, at the concentration of 3ppm and 7.5ppm, the removal rate decreased gradually, and then the removal rate showed an upward trend. When PH was 9.1 and 10.1, the removal rate of phosphorus showed a slow downward trend with the increase of the concentration. Key words: Calcite; phosphorus; adsorption / desorption;kinetics 1引言 富营养化导致水体恶化是数十年来引起各国学者所关注的水环境污染问题[1]。它不仅使水体丧失应有功能, 而且使水体生态环境向不利于人类的方向演变[2]。磷是水体富营养化的主要控制因素， 所以废水除磷是预防水体富营养化的重要手段[3]。根据英国国家环境署规定，静止水体总磷浓度 0.086mg/l 为水体富营养化的临界值[4]。而佛西川等在七十年代初期对磷与藻类生长相关性的研究, 当水体中磷浓度低于0.003mg/L时, 就可能限制藻类的生长[5]。在我国，大部分河流和湖泊都处于半富营养化或营养化的状态。是以，找到一种高效去除水体中磷元素的方法对控制磷污染有重要的指导意义。 1.1方解石的基本性质 方解石的分布十分广泛，是一种