不同官能团MOF对质子交换膜NAFION膜的改性.docVIP

PAGE PAGE 28 不同官能团MOF对质子交换膜NAFION膜的改性 摘要 燃料电池作为一种高效、清洁能源，在生活、生产中的作用越来越得到人们的关注。其中，质子交换膜是燃料电池的核心部件之一，其性能直接决定燃料电池的运行性能。本文首先介绍了燃料电池的发展历史，现状，并分析了其核心部件质子交换膜中，当前最具代表性的全氟磺酸膜Nafion的优势与缺陷。在此基础上，提出本文的研究思路：利用不同官能团的MOF改性Nafion基质子交换膜，并深入探讨了MOF不同功能基团在Nafion膜中的质子传导贡献及机理。本文先制备了UiO-66，UiO-66-NH2，UiO-66-NO2，UiO-66-SO3H四种具有不同官能团的MOF，并通过XRD等方法对其结构进行了表征，之后，探讨了UiO-66-NH2（即同一种官能团-NH2）的不同添加比例对Nafion膜的性能及结构的影响，从溶胀率，含水率，质子传导率，甲醇渗透率等方面进行分析和探讨，并得出结论，选择出0.6%比例为最优配比。之后又在最佳比例0.6%的条件下，探讨不同MOF的官能团，-SO3H，-NH2,-NO2,-H对Nafion膜性能及结构的影响，结果表明明显的得到磺酸根取代的质子传导率较高，而经过分析，原因即它的非常强的亲水性和显而易见的酸性，可以导致形成高密度的氢键网状结构。而且，它的极端多孔性和尺寸作用，也包括一定数量的MOF中的官能团，也大幅度的提升了质子传导率。同时大量的含有丰富氧原子的Zr6O4(OH)4(CO2)12团簇，也是增强氢键形成的原因之一。最终根据之前的结论，得出选择带有-SO3H官能团MOF为最适宜改性Nafion膜的结论。 关键词：燃料电池，Nafion质子交换膜，UiO-66，质子传导率，甲醇渗透率 The Modification Of Proton Exchanged Membrane——Nafion Through Different Functional Groups ABSTRACT This paper talks about the history, status quo, and future prospects of fuel cell. So that it’s important and interesting to select proton exchanged membrane which is nearly the most important equipment to determine the properties’ of the membrane. And through this theme, it discusses why and how to choose better metal of framework and the conclusion about them. Herein, the tests of UiO-66-NH2 (with the same functional group) in different proportions are included swelling ratio, and?water uptake, proton conductivity, methanol permeability,etc. The conclusion is that I choose the 0.6% as the best proportion. Then in the proportion of 0.6%, I change and make the product of different functional groups, like -HSO3,-NH2,-NO2,-H. I take advantage of the previous methods to explore which functional group is the suitable one for producing proton exchanged membrane. Through analysis, -SO3H has its obvious acidity and extremely intrinsic hydrophilic property, which lead to high-density hydrogen-bonding networks. Besides, the polarity and size effect bonding networks, as well as the number of functional groups in the MOF framework have an i