水溶性导电聚苯胺-碳纳米管复合材料的制备与性能研究论文.docVIP

题目：水溶性导电聚苯胺/碳纳米管复合材料的制备与性能研究 PAGE PAGE I PAGE PAGE I 水溶性导电聚苯胺/碳纳米管复合材料的制备与性能研究 摘 要 导电聚苯胺/碳纳米管复合材料具有广阔的应用前景。本课题采用原位聚合方法合成聚苯胺/碳纳米管复合物。在苯胺的盐酸溶液中，用过硫酸铵作引发剂，在碳纳米管上原位聚合生成聚苯胺，制备导电聚苯胺/碳纳米管复合材料。通过改变碳纳米管和苯胺的质量比，合成不同碳纳米管含量的聚苯胺/碳纳米管复合物。然后再用水性掺杂剂进行掺杂得到聚苯胺/碳纳米管水溶液，干燥后得到复合物薄膜。之后运用红外、紫外、透射电镜对其结构进行表征，并进行TG、电导率的测试。 结果表明制备出的聚苯胺/碳纳米管复合物具有良好的导电性。电导率的测定结果表明，在碳纳米管与苯胺的质量比为0.8%时聚苯胺、碳纳米管复合材料的导电性能相对纯聚苯胺有很大的提高。 关键词：碳纳米管；聚苯胺；导电复合物；原位聚合 PAGE PAGE II Study on Synthesis and Capacitance Performance of Carbon Nanotubes /Polyaniline Composite Abstract The CNTs/PANI composite has wide application prospect. The topic is in situ polymerization of Polyaniline /carbon nanotube composite. The composite materials of CNTs/PANI were prepared by the in-situ polymerization. The content of carbon nanotubes by changing the mass ratio of carbon nanotubes and polyaniline synthesis of different carbon nanotubes/conductive polyaniline composite. Using water-based dopant doped polyaniline/carbon nanotube aqueous solution, get compound film after drying. Using the infrared, ultraviolet,and transmission electron microscopy (sem) to its structure characterization, and TG,electrical conductivity test. The result show that the prepared carbon nanotubes/conductive polyaniline composite has good electrical conductivity. The results show that, the conductivity of polyaniline is greatly improved, with the 0.8% content of CNTs in the CNTs/PANI composites and is best. Key words: carbon nanotubes; Polyaniline; Conductive composites PAGE PAGE IV 目 录 TOC \o 1-3 \h \u 25152 1 绪论 1 14932 1.1引言 1 1249 1.2碳纳米管 1 30413 1.2.1碳纳米管的研究背景 1 3712 1.2.2碳纳米管的结构与特性 1 6257 1.2.3碳纳米管的制备 2 31537 1.2.4 碳纳米管的应用前景 3 13862 1.3聚苯胺 4 27871 1.3.1聚苯胺的研究基础 4 7770 1.3.2聚苯胺的结构与性能 4 9126 1.3.3聚苯胺的制备方法 5 13952 1.3.4聚苯胺的应用 6 1511 1.4聚苯胺复合材料的应用 8 28481 1.5本论文研究意义及主要内容 9 7728 1.5.1本论文的研究意义 9 15193 1.5.2本论文研究的主要内容 9 25900 2 实验部分 10 9785 2.1实验原理 10 8240 2.2实验主要