四唑-叠氮混合桥联的配合物分子磁体合成及表征论文.docVIP

PAGE PAGE I 题目：四唑-叠氮混合桥联的配合物分子磁体合成及表征 四唑-叠氮混合桥联的配合物分子磁体合成及表征 摘 要 分子磁性材料是一类通过化学方法将自由基或顺磁离子( 包括过渡金属离子和稀土金属离子) 及抗磁配体以自发组装和控制组装的方式组合而形成的磁性化合物。由于较传统磁体有着密度小、透明度高、溶解性好、易于加工、可控性好等优点，并有望在航天材料、微波材料、信息记录材料、光磁及电磁材料等领域得到应用，所以近年来对分子磁性的研究已经成为化学、物理学以及材料科学等多个领域研究的热点之一。 本论文应用叠氮桥联与四唑混合配位形成单链磁体。其中顺磁性金属配合物的研究主要集中在桥联多核金属配合物上，它们的特点是桥联配体属于抗磁性，而未配对的电子主要集中在金属磁中心上。多核金属配合物的自旋偶合通过抗磁性的桥联配体，使金属之间形成一种弱的相互偶合作用。在其构建单元时，可以形成单核、双核及多核配合物。由这些高自旋的配位物进行适当的分子组装．可以形成一维、二维及三维分子磁体，也能够形成链状或层状结构。 关键词：配位聚合物；分子磁性材料；单链磁体；四唑-叠氮混合桥联 PAGE PAGE IV Tetrazole - Complex Synthesis and Characterization of Molecular Magnets Mixed Bridged Azide Abstract Magnetic material is a magnetic molecule by chemical compounds such as free radical or paramagnetic ions (including rare earth metal ions and transition metal ions) and the diamagnetic ligand spontaneous assembly and control assembly formed by a combination manner. Due to the more traditional magnet has a low density, high transparency, good solubility, easy processing, good controllability, etc., and is expected to be applied in the field of aerospace materials, microwave materials, information recording materials, magneto-optical and magnetic materials, etc. So in recent years, to the study of molecular magnetism has become one of the hot chemistry, physics and materials science and other fields. This thesis applies azide bridging ligands with tetrazole mixed to form a single -chain magnet. Which study paramagnetic metal complexes focused on bridging polynuclear metal complexes, which are characterized by bridging ligands are diamagnetic, but not paired electrons focused on the metal magnetic center. Polynuclear metal complexes of anti -magnetic spin-spin coupling through bridging ligands, so that the formation of a weak mutual coupling effects between the metals. In its building blocks, you can form a single core, dual core and polynuclear complexes. Appropriate molecular assembly of these high -spin complex matter. Can form a one-dimensional, two-dimensi