新型可见光催化剂制备及其处理有机污染物性能研究.docVIP

PAGE PAGE 19 新型可见光催化剂制备及其处理有机污染物性能研究 摘要：近年来，水体中有机物污染严重，尤其是酚类有机物，是一类常见的高毒性且难于被降解的有机物，严重威胁着人们的健康，已成为一个十分严峻的环境问题。当前用来降解此类酚类有机物的方法主要是物化法、化学法和生化法。其中光催化降解含酚废水是一种前景良好的方法，含酚废水的光催化降解研究在国内外的光催化水处理研究中都较普遍。光催化氧化法具有能耗低、操作简便、反应条件温和等特点，成为最有前景的水处理技术之一。本文以以低浓度含酚废水为处理对象，以10%CsPM0（1:3）/Bi203为光催化剂，在可见光源的照射下，考察了光强，溶液初始浓度、、溶液初始 pH、氧气含量、不同捕获剂对苯酚降解率的影响。光催化法处理低浓度苯酚废水的效果显著，通过对其影响因素进行相应研究，有助于进一步探索提高光催化法的降解率，对处理有机废水有着较好的指导作用 关键词：有机物；苯酚；光催化；氧化铋 Novel visible catalyst preparation and properties of organic pollutants Abstract:In recent years, organic water pollution, especially phenols, is a common and highly toxic organic compounds difficult to be degraded for a class, a serious threat to peoples health, has become a very serious environmental problem. Currently used method for the degradation of these phenols are mainly chemical method, chemical and biochemical methods. Wherein the photocatalytic degradation of phenol wastewater is a good prospect method, photocatalytic degradation of phenol wastewater research in photocatalytic water treatment research at home and abroad it is more common. Photocatalytic Oxidation with low energy consumption, simple operation, mild reaction conditions, etc., has become one of the most promising water treatment technologies. In this paper, a low concentration of phenol wastewater treatment target to 10% CsPM0 (1: 3) / Bi203 as photocatalyst under visible light irradiation were investigated intensity, initial concentration ,, initial solution pH, oxygen content , different capture agents on phenol degradation rate. Photocatalytic treatment of low concentration of phenol wastewater significant effect, studied by the corresponding factors contribute to further explore an increased degradation of photocatalytic method for the treatment of organic waste has a good role in guiding. Keywords: Organics; phenol; photocatalysis; bismuth oxide 1引言 1.1研究背景和意义 随着社会经济的不断发展，人类对于资源的开发利用规模空前巨大，而随之产生了一系列的环境问题。就我国而言，急需正视并处理水体污染现状：我国已被列为全球严重缺水的国家之一，虽然我国整体水资源位居世界第六，然而由于人口基数极为庞大