液相吸收同时脱硫脱硝实验研究.docVIP

PAGE PAGE 20 液相吸收同时脱硫脱硝实验研究 摘要：主要研究了亚硫酸钠溶液、亚硫酸氢钠溶液对NOx气体的脱除研究，包括吸收液浓度、气体初始浓度以及烟气中NO/NO2配比对NOx混合气体脱除效率的影响；另外对NaOH同时脱硫脱硝实验进行了研究，并分析了同时脱硫脱硝反应过程。实验研究结果表明：以NaOH、Na2SO3或NaHSO3作为吸收剂时，纯NO的脱除率最高不超过7%，并且随着吸收液浓度的变化，NO脱除率无明显变化，而纯NO2的脱除率随着吸收剂浓度的增大而增大，并且在同浓度下Na2SO3对NO2的脱除效率最佳，NaOH的脱除效果最差。NO的脱除率随着NO/NO2配比的减小而增大，NO2的脱除率随着NO/NO2配比的减小、NO2初始浓度的增加而减小。在同时脱硫脱硝实验过程中，氢氧化钠溶液会与SO2反应生成亚硫酸钠，并最终生成亚硫酸氢钠，有助于还原NO2，且NO2的脱除率随SO2初始浓度的增大而增大，表明SO2对NO2的脱除存在协同作用；而SO2脱除效率随SO2初始浓度的增大而减小。 关键词：氧化剂；吸收剂；同时脱硫脱硝；反应机制 Experimental study about simultaneous desulfurization and denitration by liquid absorption Abstract: This paper mainly investigated the removal of NOx gases by sodium sulfite solution and sodium bisulfite solution, including some reactive parameters, such as the absorbent concentration, the initial concentration of NOx and the flue gas NO / NO2 ratio on NOx removal efficiency. In addition to NaOH simultaneous desulfurization and denitrification of experiments were studied, and the process of simultaneous desulfurization and denitration reaction were also analyzed. The results showed that: When NaOH, Na2SO3 or NaHSO3 as an absorbent, pure NO removal rate not exceeding 7%, and with the change of the absorption liquid concentration, NO removal was no significant change, while the pure NO2 removal rate increases with the absorption concentration increases; And while at the same concentration, Na2SO3 has the best removal efficiency, NaOH is the worst. NO removal efficiency was increase with the decrease of NO/NO2 ratio, NO2 removal rate increases with the decrease of NO/NO2 ratio and with the increases of the NO2 initial concentration. In the simultaneous desulfurization and denitrification experiment, sodium hydroxide solution and SO2 will react sodium sulfite, and the resulting sodium bisulfite, help restore NO2, and NO2 removal rate increase with SO2 initial concentration increases, SO2 show a synergistic effect for NO2 removal; and SO2 removal efficiency decreases with the increase of initial con