一种可见响应光催化电极的制备及性能研究.docVIP

PAGE PAGE 23 一种可见响应光催化电极的制备及性能研究 摘要：光催化技术是一门十分实用、有广阔应用前景的技术。本实验制备一种较高可见光响应的催化电极并进行其催化降解性能的研究。通过阳极氧化法制备TiO2 纳米管，并在此基础上进行非金属N、F、C的共掺杂，并沉积贵金属Au，制备Au-C/NF-TiO2电极。光电流实验表明所制复合电极在可见光照射下具有较强的响应。对Au-C/NF-TiO2优选电极进了不同载C量的研究，找出最佳的电极制备条件。随后进行Au-C/NF-TiO2电极对Cr6+ 的催化还原实验，结果表明优选电极对Cr6+ 的催化还原十分有效，Cr6+去除结果与光电流实验相吻合。随后对电极的催化影响因素：pH、电压、光电协同性进行实验探究。最后通过循环使用实验证明了所制Au-C/NF-TiO2电极具有稳定性和可循环性。 关键词：光催化；TiO2；光电流；催化反应；影响因素 Preparation and property of a visible light responsive photocatalytic electrode Abstract: Photocatalytic technology is a very practical,promising technology. The experiment for the preparation of a high visible light response catalytic electrode and the study of its catalytic degradation. Preparation of TiO2 nanotubes by anodization,doping the non-metallic N,F,C and the noble metal deposition Au,complet the Au-C/NF-TiO2 electrode preparation.Photocurrent experiments make it clear that the composite electrode have a strong photoelectric response under visible light. The Au-C/NF-TiO2 electrode was investigated in optimization of different C amounts, to find out the optimal conditions for preparation of electrode. Subsequent conducted reduction experiments of Au-C/NF-TiO2 electrode on Cr6+, the results show that the catalytic reduction of Cr6+ is effective in the optimization of electrode, the reduction results coincide with the experimental photocurrent.Then the catalytic effect on the electrode factors: pH, voltage, photoelectric collaborative inquiry experiments. Finally, the recycling experiment proved that the Au-C/NF-TiO2 electrode has the stability and recyclability. Keywords: The photoelectric catalysis; TiO2 ; Photocurrent ; Catalytic reaction; Influence factors 1引言 1.1研究背景和意义 近年来，由于降解能力十分突出、能耗比较低、循环寿命较长等特点，光催化技术[1]逐渐走进人们的视野，成为我们关注的焦点。其中，TiO2以物化性质稳定、安全无毒、廉价、光催化活性高、循环利用等优点成为最受欢迎的纳米光催化剂，被广泛应用于水污染治理。但是，由于较低的太阳光利用率以及较高的光生电子-空穴对复合率等原因使TiO2光催剂的实用性被大大的限制。粉体TiO2存在回收复杂、难以重复利用等不足。 新型的纳米管、纳米线、纳米带这些一维纳米结构[2]，由于其具有良好的光吸收性能，十分独特的尺寸效应以及较高的比表面积，有望解决上述难题。不仅这些结构能够起到提高吸收效率的作用，另一方面对材料