有机硅改性水性环氧丙烯酸树脂的制备与性能.docVIP

PAGE PAGE 26 有机硅改性水性环氧丙烯酸树脂的制备与性能 摘要：本文主要研究用KH560对水性光固化丙烯酸树脂进行改性合成一种用KH560改性水性光固化丙烯酸树脂，探究了反应温度对反应的影响，并对产物结构进行了红外表征，测试了产物涂膜进行了吸水率、水接触角、凝胶含量、力学性能以及TG分析。研究表明：反应的最佳温度为80℃ 关键词：硅改性；水性；丙烯酸树脂；光固化；性能 ABSTRACT: In his research, a kind of KH560 modified UV-curable waterborne epoxy acrylic resin has been synthesized . At the same time, the research of the temperature and Silicon content which showed us 80℃ and 20% Silicon content is the best temperature and Silicon content on this synthetic reaction. The molecular structure of the Silicone-modified polymer was analyzed by using FTIR spectroscopy. The results told us the KH560 has been introduced into the main chain of the molecule of this polymer. Besides,after introducing KH560 into the polymers, the water absorption has been reduced to 10.09%,and the water contact angle has been improved to 70%.At the same time,the mechanical behavior also has been improved.Including the flexibility has been improved to be best, the hardness has been improved to 6H, impact resistance has maintained at 50cm, adhesion has been improved to 0 level.after all,all of these abilities has been better than the pure polymers.These analyzes has show us by introducing KH560, Silicon modified UV-curable waterborne epoxy acrylic resin’s performance has been improved.After that ,by using the analysis of TG, we have learn that the thermal stability has also been improved for introducing KH5 Key words: Silicon modified,；Epoxy； UV-Curable； Acrylic resin；Properties 1 引言 1.1 水性紫外光固化涂料及其树脂 由于科技的不断发展，涂料的类型也在不断的增加着，除此之外，涂料的应用范围也在不断地增大着，由此可以得出一个结论：在一定的程度上，可以用一个国家的涂料消费水平来衡量这个国家的经济发展水平[1]。 早在2010年，我国有关部门就统计过，每年涂料的产量就超过200万吨，而在这些涂料当中，绝大部分都是工业用的涂料，另外，在该统计在数据中表明，每年涂料的增长速度也非常快，平均为每年3.4％[2]。由于全世界的环境污染问题越来越严峻，人们也越来越关注这个问题。因此，也对涂料行业的环境保护问题造成了非常严峻的考验。其中主要的原因是传统溶剂型的涂料含有一定量的VOC，即挥发性有机物，在涂料固化时挥发性有机物会大量排放造成严重的环境污染。正是由于这个原因，市场中的传统溶剂型涂料占的份额正在逐渐减少，除此之外，紫外光固化涂料、水性涂料、粉末涂料，还有高固体组分涂料这些排放挥发性有机物比较少的涂料的市场份额也在缓慢提升[3]。 紫外光固化涂料[4][5]，由于其是一种在紫外光照射的条件下，能在短时间内发生一系列物理变化和化学交联固化的涂料，它也还有另外一个名称为U