[超分子化学与晶体工程基础]-超分子异构现象.pptxVIP

5. 超分子异构现象;异构现象(isomerism)、异构体 (isomers);;cis — 二氯二氨合铂 棕黄色，? 0 S = 0.2523 g/100 g H2O 具抗癌活性(干扰DNA复制);[CoCl3·2 (H2NCH2CH2NH2): 立体异构体的指认，有力地支持配位理论;;固体的多晶型现象;A model for crystallization;;在给定条件下，多组分体系中不同组分（构筑模块）之间，通过配位键、超分子作 用等的导向，进行自组装，形成分子聚集体的过程。;Structural control supramolecular isomerism in low-dimension;;Supramolecular isomers [CuI(2-pytz)];;;;添加剂对配位聚合物结构的影响;溶剂效应;Structures of [Cu(eim)];;;;;;;;;Coordination geometries of metal ions Ligand structures and chemical properties: ? appropriate bridging ligands ? appropriate combination of bridging and terminal ligands ? geometric and bulkiness of the ligands Reaction conditions temperature, pH, templates, counter ions, solvent, etc. Simple in principle, complicated in practice;