气体的临界常数包括临界温度.docVIP

气体的临界常数包括临界温度 气体的临界常数包括临界温度、临界压力、临界摩尔体积等。临界温度是指在这个温度之上，无论加多大的压力都不能使气体液化的温度。临界压力是指气体在临界温度之下液化时所需的最低压力。临界摩尔体积是指气体在临界温度、临界压力之下1摩尔的体积，可以由临界密度来计算。 临界温度、临界压力、临界摩尔体积是指共存的气相与液相的密度正好相等时的热力学温度、压力和摩尔体积的值。 单质气体的临界常数 Critical Constants of Elementary Substance Gases 临界温度 临界压力 临界密度 分子式 序号(Critical temperature) (Criticalpressure) (Critical density) (Molecular (No.) 6formula) T/? p/(10Pa) ρ/(g/ml) ccc1 Ar -122.4 4.8734 0.533 2 As 530.0 34.651 - 3 Br 311.0 10.334 1.26 2 4 Cs 1806.0 - 0.44 5 Cl 144.0 7.7003 0.573 2 6 D -234.9 1.6515 0.669 2 7 F -128.85 5.2149 0.574 2 8 H -240.17 1.2928 0.0314 2 9 He -267.96 0.22695 0.0698 310 He -269.84 0.11449 0.0414 11 Hg 1462.0 18.946 - 12 I 546.0 - 1.64 2 13 K 1950.0 16.211 0.187 14 Kr -63.8 5.5016 0.919 15 Li 2950.0 68.897 0.105 16 N -147.0 3.3942 0.313 2 17 Na 2300.0 35.462 0.198 18 Ne -228.75 2.7559 0.484 19 O -118.57 5.0426 0.436 2 20 O -12.1 5.5726 0.54 3 21 P 721.0 - - 22 Ra 104.0 6.2818 - 23 Rb 1832.0 - 0.34 24 S 1041.0 11.753 - 25 Si -3.5 4.8430 - 26 Xe 16.583 5.8400 1.11 无机化合物气体的临界常数 Critical Constants of Inorganic Compound Gases 临界压临界密临界温度 临界压力临界密度临界温度分子式力度分子式(Critical (Critical (Critical (Critical (Molecular (Critical (Critical (Molecular temperature) pressure) density) formula) temperature)T/? pressure) density) formula) c6p/(10Pa) ρ/(g/ml) T/? cc6cp/(10Pa) ρ/(g/ml) cc 空气(Air) -140.6 3.7691 0.313 HfCl 450.0 5.7752 1.05 4AlBr 356.0 2.6343 0.510 HgCl 700.0 - 1.56 32AlCl 490.0 2.8876 0.860 NF -39.2 4.5290 - 33AsCl 318.0 - 0.720 NH 132.4 11.276 0.235 33BBr 300.0 - 0.90 NO -93.0 6.4844 0.52 3 BCl 178.8 38.704 - NO 158.0 10.132 0.55 32BF -12.3 4.9849 - NF 36.2 3.7488 - 324BH 16.6 4.0528 - NH 380.0 14.691 - 2624BiCl 906.0 11.955 1.21 NO 36.41 7.2443 0.452 32(CN) 127 5.9778 - PH 51.6 6.5351 - 23CO -140.24 3.4985 0.301 SF 45.54 3.7589 0.736 6CO 31.0 7.3760 0.468 SO 157.6 7.8837 0.525 22COS 102.0 5.8765 0.44 SO 217.8 8.2069 0.63 3GeCl 279.0 3.8501 0.65 SbCl 521.0 - 0.84 43HBr 90.0 8.5514 - SiClF 34.5 3.4651 - 3HCl 51.5 8.3082 0.45 SiClF