金属-有机骨架材料MOF-5合成及CO2吸附性能研究.docx

1/25 范文最新推荐 金属-有机骨架材料 MOF-5 合成及 CO2 吸附性能研究 近年来，由于温室气体的大量排放引发的环境问题 越来越严重。其中CO2 是温室气体的主要成分。所以 CO2 的分离与捕集技术是全球科学家都在关注的课 题。金属-有机骨架材料 (MOFs) 是一种新型的多孔 材料，具有较大比表面积和孔隙率以及稳定的物理、 化学性能， 是一种很有潜能的气体吸附材料。本论文 通 过 实 验 手 段 对 一 种 典 型 的 MOFs 材 料 mdash;MOF-5 材料进行研究，探讨最优合成条件以 及吸附过程中各种工艺条件的影响。结果表明：温度 为120℃,对苯二甲酸 (H2BDC) 的浓度为0.02 mol/L, 反应时间为20h 以上时合成出的MOF-5 晶体具有较完 整的晶体结构以及较高的CO2 吸附量。吸附过程工艺 条件方面，在实验范围内，降低吸附温度、增加进口 气体的 CO2 浓度或减小气体流速有利于MOF-5 吸附 CO2 。6979 关键词 CO2 金属-有机骨架材料MOFsMOF-5 吸附 毕业设计说明书(论文)外文摘要 Title Synthesis and CO2 adsorption properties of Metal-organic framework material MOF-5 Abstract In recent years, due to increasingly serious environmental problems caused by greenhouse gas emissions,CO2 separation and capture technologies are concerned by the scientists around the world. Metal-organic framework materials (MOFs)are a new type of porous materials, with large surface area, porosity as well as stable physical and chemical properties. MOFs are great potential materials for gas adsorption. In this paper,a typical MOFs material MOF-5 was studied by experimental means, including the optimal synthesis conditions and the influence of adsorption process conditions. The results show that when temperature was 120℃,terephthalic acid (H2BDC) concentration was 0.02 mol/L and reaction time 3/25 范文最新推荐 was more than 20h,the synthesized MOF-5 crystals had more complete crystal structure and higher CO2 adsorption capacity. In the aspect of adsorption process conditions, within the experimental range, decreasing adsorption temperature, increasing the CO2 concentration of the feed gas inlet or decreasing feed gas flow rate was favorable for the adsorption of CO2 in MOF-5. 3.3.2 MOF-5样品表征22 3.3 吸附实验装置及数据分析方法25 3.3.1 实验装置25 3.3.2 实验数据分析方法26 3.4实验结果与讨论26 3.4.1 MOF-5再生性能26 3.4.2 温