钛酸铋钠基无铅压电陶瓷研究进展.pdfVIP

摘 要 钛酸铋钠基无铅压电陶瓷是压电材料中的一种关键的，具有广泛应用的功 材料，能实现电能与机械能之间的相互转换。本文主要综述压电陶瓷的基础概念 （压电性和铁电性）、主要结构以及应用方面的发展过程及现状。如今锆钛酸铅 （PZT ）是人们最为熟悉且用量最大的功能材料，尽管PZT 基材料具有优良的性 质、较好接受的价格，但是 PZT 含有大量的有害物质铅，所以在制备、使用和 处理过程中不可避免地引起一系列违背环境友好型发展问题。因此，研究对环境 友好和对人类无害的无铅压电材料引起了越来越多的关注。自 21 世纪初以来， 无铅压电材料的研发逐渐的有了快速发展，很快的应用在了一些领域并且效益也 很让人满意。本文主要以钛酸铋钠基无铅压电陶瓷（BNT ）为例，讲述有关无铅 压电陶瓷的基础理论、离子掺杂和应用于储能电容器方面的研究进展及现状以及 今后发展的方向和目标做出展望和研究方向。 关键词：铁电性和压电性 ；BNT ；无铅压电陶瓷；掺杂；储能型电容器 I Abstract Bismuth sodium titanate lead-free piezoelectric ceramics (PZT) is a key functional material in piezoelectric materials, which can realize the mutual conversion between electrical energy and mechanical energy. In this paper, the basic concepts (piezoelectric and ferroelectric), main structures and applications of piezoelectric ceramics are reviewed. Today, lead zirconate titanate (PZT) is the most familiar and most used functional material. Despite the excellent electrical properties of PZT based materials, the content of lead oxide is extremely high , which inevitably causes environmental problems in the process of preparation, use and treatment. Therefore, lead-free piezoelectric materials have attracted more and more attention. Since 2000, research and development of lead-free piezoelectric materials has made significant progress, this article mainly sodium bismuth titanate based lead-free piezoelectric ceramics (BNT) as an example, the story about the basic theory and application of lead-free piezoelectric ceramics in temperature stable progress of capacitor and the energy storage capacitor and the present situation and future development direction and goals to make prospects and research direction. Key words: Ferroelec