有机光电半导体材料及其未来之应用.pptxVIP

有机光电半导体材料及其未来之应用第1页/共39页 T.-F. Guo2OutlinesSemiconductors Organic semiconductors (energy and delocalization of charge carriers)OLEDs and PLEDs 基礎原理和應用Organnic photovoltaic and solar cellsConclusions第2页/共39页 T.-F. Guo3Fundamental science of inorganic semiconductors第3页/共39页 T.-F. Guo4Typical Semiconducting Materials第4页/共39页 T.-F. Guo5Energy Band Diagram of a conductor, semiconductor, and insulator(a) a conductor(b) a semiconductor(c) an insulator第5页/共39页 T.-F. Guo6Beginning of orgnaic semiconductor (π bonding)Side-by-Side Bonding第6页/共39页 T.-F. Guo7Conjugated (共軛): alternatively double-single bondsCHCHCHCHCHCH雙鍵單鍵 第7页/共39页 T.-F. Guo8Bang Gap of Polyacetylene………..……Band Gap第8页/共39页 T.-F. Guo9Conjugated polymerSigma bondDelocalized ? electron cloudhttp://www.cdtltd.co.ukAlternating single-double bonds第9页/共39页 T.-F. Guo10Creating new materials from old materialsnEg = 2.4 eVPPVOR1nOEg = 2.1 eVR2R1nEg = 2.4 eVR2nEg = 3.0 eVPPPnEg = 1.4 eVPAThrough the structure engineering, polymers with different emitting colors were synthesized.第10页/共39页 T.-F. Guo11Delocalization of Charge Carriers in PolyacetyleneLocalized! Charge cannot go anywhere!!!Delocalized! Charge carriers can move around!!!第11页/共39页 T.-F. Guo12Delocalization and Transport of Charge Carriers第12页/共39页 T.-F. Guo13Conjugated Polymers: Basic Materials and ChemistryConduction polymers: Polyacetylene, Polyaniline, PEDOT/PSS… etc.Semiconducting polymers: Polythiophenes, Oligothiophenes… etc.Light-emitting/Photovoltaic Polymers: Poly-(para-phenylene-vinylene), Poly(para-phenylene), Polyfluorene… etc. 第13页/共39页 T.-F. Guo14Scientific Interest in Organic Materials1950’s – steady work on crystalline organics starts1970’s – organic photoconductors (Xerography)1980’s – organic non-linear optical materials1987 – Kodak first published the efficient organic light-emitting devices (OLED)1990 – Cambridge groups publish the first polymer light-emitting diodes (PLED)Since then, the field has dramatically expanded both commer