TB585：回收水中聚丙烯酰胺.pdfVIP

Technical Bulletin TB585: Determination of Residual Polyacrylamides in Reclaimed Water Keywords SEC, UV, PL aquagel-OH, Polyacrylamides, Aqueous Polyacrylamides are often used as settling aids in water Acrylamides exhibit strong UV absorbance at low clarifi cation processes. The polymers act as fl occulants wavelengths, however, the limiting factor in the to help remove contaminants from the water stream. determination of trace polyacrylamides is purely down to Residual polyacrylamides in the reclaimed water can detector sensitivity. affect subsequent processing operations and have an obvious environmental impact. A fast analytical method Column: PL aquagel-OH 50 8µm, 300x7.5mm is therefore required to monitor traces of residual (1149-6850) polyacrylamide in reclaimed water. Eluent: 0.05M Na SO , adjusted to pH 3 2 4 Flow Rate: 1.0ml/min Aqueous size exclusion chromatography (SEC) is a Sample Loading: 0.1mg/ml, 200µl well documented technique for the characterization of Detector: UV, 208nm polyacrylamide molecular weight distribution. In this particular application, the primary aim is to quantify the amount of residual polymer, whereas the molecular Polyacrylamides Low MW Species weight information is of little importance. A single pore size aqueous SEC column was selected to partially exclude the polymer peak and thereby give increased Nonionic res