SCI论文写作与投稿 第2版-课件 6-SCI论文结论写作 .pptx

;;;;;;;;;;;;;CONCLUSIONS

EnvironmentalfriendlySiNCswithaspectrallylimitedemissionprofilecanbeturnedintoaphosphorwithawell-balancedvisiblewhiteemissionspectrumupone-beamirradiation.Thespectralchangesinducedbythee-beamirradiationconsistofaconsiderablespectralshiftaswellasbroadening,irrespectiveoftheinitialsamplecharacteristics.WeconcludethattheirradiationcreatesnewcolorcentersintheoxideshelloftheO-SiNC,sincetheoxide-freeorganicallycappedC-SiNCsdonotshowanychangeintheiremissionspectrumuponirradiationandemissionfromdefectcentersgeneratedinthenativeoxidethinfilmontheSisubstrateisnegligible.Thesedefectscanberelatedtowell-knowncolorcentersinbulkandnanostructuredsilica.Unlikeinsilica,however,thesecolorsitescanbeefficientlyopticallyexcitedintheSiNCsystemsat405?nmbyalowpowerlaserdiode,duetothenarrowerbandgapofthehost.FromthecomparisonofthethreeverydifferentO-SiNCsamples,wefoundthiseffecttobeindependentofthepreparationprotocolandpropertiesofeachparticulartypeofO-SiNC,withsmallvariations:whereasthegreenbandemissionbenefitedfromthickerandpossiblymorestrainedsilicashells,redandbluebandsappearedinallsamples,withthebluebandbeingexceptionallywell-developedandstableinair.Wethusbelievethatanyoxide-cappedSiNC,treatedbyane-beamwithanenergyofaround15?keVforafewminutescanbeconvertedintoabrightlywarm-whitelight-emittingmaterial,especiallyprovidedathickersilicashell.Thisconstitutesanovel,robust,andreliablemethodtoconvertanyenvironmentalfriendlyandabundant(oxide-capped)SiNCsintoawhitecolorphosphor.Furtheroptimizationofthematerialandemissionyieldsisnecessary,however,thecurrentstudyshowsthatthiseffectoffersmanypropertiessoughtbywhite-lightapplications.;第一、二句描述实验结果：具有光谱限制发射剖面的环境友好型SiNCs可转化为在电子束照射下具有均衡可见白色发