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BoltzmannStatisticsIdeal
MonoatomicGas
DiannanLu
DepartmentofChemicalEngineering
Howtosolvepartitionfunctions?
Theformalismdevelopedintheprevioussectionispowerful,butthereareonlyfewcasesfor
whichwehavethemathematicalsophisticationtoactuallyevaluatethepartitionfunctions.
Modelsystem:non-interactionparticles
Coreidea:separatingthetotalenergyofthesystem(theHamiltonian,instatisticalmechanics
terminology)asasumofindependentcontributions.
Canonicalp
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