热镀锌板锆化陶瓷膜的结构及性能.pdfVIP

热镀锌板锆化陶瓷膜的结构及性能 王双红，刘常升 (1东北大学材料各向异性与织构工程教育部重点实验室，沈阳，110089) 摘要：为了替代传统的磷化处理，采用锆化工艺在热镀锌板表面制备了陶瓷膜。用扫描电镜和能谱仪分析了陶瓷膜的 组织形貌和元素组成；用极化曲线法研究了陶瓷膜的电化学性能；用中性盐雾试验和盐水浸泡实验对比考察了热镀 锌板陶瓷膜和磷化膜的耐腐蚀性能。结果表明：热镀锌板表面的陶瓷膜随锆化时间增加呈现出无色到蓝色的颜色变 化；陶瓷膜的结构主要由Zr02以及部分ZrOF,、Zn。OF：组成；极化曲线测试结果表明陶瓷膜能显著地提高热镀锌板的 耐电化学腐蚀性能；盐雾试验和盐水浸泡实验结果表明陶瓷膜的耐腐蚀性能弱于锌系磷化膜；锆化处理技术有望替 代污染较霞的磷化处理技术。 关键词：热镀锌板，氟锆酸、磷化膜、陶瓷膜 Structureand ofCeramicFilmon Performance Hot-dip GalvanizedeZinaVleetS eel WANG Shuanghong，LIUChangsheng for andTextureof of (KeyLaboratoryAnisotropy Materials，MinistryEducation，NortheasternUniversity, 11 Shenyang0089) filmwas 011 Abstract：Theceramic thesurfaceof steelthefluorozirconate prepared hot—dipgalvanizedby treatment tosubstituteconventional treatment．The and of morphology techniques phosphating composition theceramicfilmwere electron and investigatedbyscanning microscopyenergydispersivespectrometer； TheelectrochemicalcorrosionresistanceoftheceramicfilmsWastested corrosion test；The bypolarization resistanceoftheceramicfilmsWasdoneneutralsalt testand test．Theresultsshowthat by spray dipping theceramicfilm fromcolorlessbluewith treatment was to different ceramicfilm changed time；The mainly and electrochemicalcorrosionresistanceofthe compositedofZr02 ZrOF2、Zn20F2；The