Nb-Si基原位复合材料表面包埋渗Al-Si-Y涂层的组织及高温抗氧化性能.docVIP

  Nb-Si 基原位复合材料表面包埋渗 Al-Si-Y 涂层的组织及高温抗氧化性能# 王皖，周春根** 5 10 15 20 25 30 35 40 （北京航空航天大学材料科学与工程学院，北京 100191） 摘要：本文采用热力学计算的方法分析了实现 Nb-Si 基原位复合材料上 Al-Si-Y 三元包埋共 渗的可行性条件。结果表明：使用 NH4Cl 做激活剂，Al2O3 做填充剂，当渗剂成分为 10Si-3.4Al-2Y2O3-5NH4Cl-79.6Al2O3 (wt.%)时，可以在 1150的温度下实现 Al-Si-Y 三元共 渗。采用 X 射线衍射（XRD）、扫描电子显微技术（SEM）和能谱分析（EDS）等技术对 涂层进行了物相、结构和成分的分析，结果表明：制备的涂层具有多层结构，分为外层、中 层和内层。从涂层中元素的分布来看，涂层是通过 Al、Si、Y 元素向基体内扩散而形成的。 关键词：热力学计算；Nb-Si 基原位复合材料；包埋渗；共渗 中图分类号：TB35 Codeposition of Al-Si-Y on Nb-Si in situ composites by pack cementation process WANG Wan, ZHOU Chungen (Material science and engineering school, Beihang University, Beijing 100191) Abstract: In order to identify suitable halide activators and pack compositions for co-depositing Al, Si and Y to form diffusion coatings on Nb-base in situ composites by the pack cementation process, thermochemical calculation was taken to analysis the vapour pressure of halide species generated in a series of pack powder mixtures at high temperatures.The results of calculations indicated that codeposition of Al, Si and Y on Nb-Si in situ composites could be achieved at 1150?C with the pack power mixtures composed of 10Si-3.4Al-2Y2O3-5NH4Cl-79.6Al2O3 (wt.%) activated by NH4Cl. The coating deposition experiment by pack process cementation was carried out according to the analysis. XRD, SEM/EDS techniques were used to analyse the phases, structure and chemical composition of the coating. It was found that the coating obtained had amultiple layer structure, consisting of an outer layer, an middle layer, and an inner layer. It was suggested that the coating was formed via a sequential deposition mechanism through inward diffusion of Cr, Y and Si. Keywords: Thermochemical calculation; Nb-base in situ composites; Pack cementation; Co-deposition 0 引言 铌硅基超高温合金以其低密度、耐腐蚀和良好的高温强度等优点而有望成为航空、航天 等领域用高温结构材料[1-3]。然而该合金在高温下的抗氧化性能较差[4]，纯铌甚至在高 600℃ 的空气中就会发生剧烈氧化[5]，严重制约了其应用与发展。为了解决这一问题，人们主要通 过合金化或者在其表面制备涂层来提高铌硅基超高温合金抗氧化性能。但是通过合金化的方 法不能彻底解决该合金的抗氧化性问题，不仅是由于当可提高其抗氧化能力的合金