点击化学制备含Dowson型多金属氧酸盐的杂化聚合物.docVIP

  点击化学制备含 Dowson 型多金属氧酸盐的 杂化聚合物# 胡敏标，马驰，王维** 5 10 15 20 25 30 35 40 （南开大学高分子化学研究所，功能高分子材料教育部重点实验室） 摘要：多金属氧酸盐(POM)是由前过渡金属离子通过氧连接而形成的具有特定分子构型的金 属氧簇类化合物，在许多领域有着重要的应用。由于 POMs 与其他材料相容性较差和常为无 机粉末而导致可加工性较差，应用受到了极大的限制。高分子材料具有良好的可塑性和可加 工性，因此将 POM 通过物理包埋或化学键固定在高分子基质上制成杂化材料成为拓宽 POM 应用范围行之有效的方法并将得到广泛的研究。我们致力于发展可控、温和的方式来制备含 POM 的杂化聚合物的研究。以铜催化的叠氮-炔基 Husigen 环加成反应为代表的点击化学因 其高效及高选择性顺应了化学合成对分子多样性上的要求。 关键词：多金属氧酸盐；杂化聚合物；点击化学 中图分类号：O633.4 Precisely Controllable Synthesis of Dawson-Type Polyoxometalates Containing Hybrid Polymers via Click Chemistry Hu Minbiao, Ma Chi, Wang Wei (The Key Laboratory of Functional Polymer Materials and Institute of Polymer Chemistry, College of Chemistry, Nankai University) Abstract: Organic-inorganic hybrid materials have begun to play a major role in the development of advanced functional materials. Polyoxometalates(POM) are discrete and anionic metal-oxide clusters with frameworks built from transition metal oxyanions linked by shared oxide ions, which are of current interest as soluble metal oxides and for their applications in catalysis, medicinal chemistry, and materials science. Because polymers make up the most widely used class of materials due to their superior performance and processability, incorporating inorganic POM clusters into polymer chains is believed to be an efficient way to create novel hybrid materials with desirable properties and functionalities. There are various approachs to prepare such POM-polymer hybrids, including physical blending, chemical modification. But the stuctures of the hybrids obtained from these methods were indefinite, and it is a challenge to develop a novel method to prepare POM-polymer hybrids with well structures. Copper-catalyzed azide-alkynes cycloaddition (CuAAC), the prime example of “click chemistry” introduced by Sharpless and co-workers, has been utilized for preparation of POM-polymer hybrids with mild experimental conditions, functional group tolerance, various solvents (including water), high y