高效率侧链共轭聚合物的合成及光伏性能研究.docVIP

  Synthesis and photovoltaic performances of high efficiencies  5 conjugated copolymers with side groups# LI Haohao1, LUO Hao2, CAO Zhencai1, GU Zhaojie1, SHEN Ping3, ZHAO Bin3, CHEN Huajie2, YU Gui2, TAN Songting3** (1. College of Chemistry, Xiangtan University, HuNan XiangTan 411105; 2. Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190; 3. Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of  10  Abstract: Education, HuNan XiangTan 411105) Three new copolymers (PT-TPA, PT-DTBT and PT-DTBTTPA) of benzo[1,2-b:4,5-b]dithiophene (BDT) and thiophene with different conjugated side chains (di(p-tolyl)phenylamine (TPA), 4,7-dithien-5-yl-2,1,3-benzodiathiazole (DTBT) and DTBT-TPA) were synthesized via the Stille coupling polymerization. The TPA and the DTBT were introduced to  15 20 25 30 35 40 improve the hole-transport ability and broaden the absorption spectrum. The effects of different conjugated side groups on thermal, optical, electrochemical, hole-transporting and photovoltaic properties of these copolymers were investigated. It was found that the copolymer PT-DTBTTPA containing TPA and DTBT in the side chain showed the highest hole mobility. The three copolymers exhibit deep HOMO energy levels, which were effectively tuned by changing the side groups. Photovoltaic cells were fabricated with the synthesized copolymers as electron donors and [6,6]-phenyl-C-butyric acid methyl ester (PCBM) as the electron acceptor. Bulk heterojunction polymer solar cells based on PT-DTBT and PT-DTBTTPA showed promising power conversion e?ciencies of 5.50% and 5.16%, respectively. Keywords: side chains; synthesis; polymer solar cells; photovoltaic performances 0 Introduction Bulk heterojunction (BHJ) polymer solar cells (PSCs) based on conjugated copolymers as donors and fullerene derivative as an acceptor[1] have been intensively studied in recent years for their low-cost, lightweight, mechanical flexibility, fast/chea