壳聚糖酰化膜的性能研究.pdfVIP

壳聚糖酰化膜的性能研究 摘 要 壳聚糖是甲壳素脱乙酰后的产物,不溶于水和碱性溶液中,但可溶于大多数稀 酸中。它是线性高分子聚合物,理化性能相对稳定,具有生物活性,可生物降解,粘合 性好,成纤成膜性能优良，已广泛应用到化工、医药、食品、发酵、污水处理等领 域。因此，很有必要对进行其更广泛的研究。 本文主要研究改性的壳聚糖膜。壳聚糖膜在乙酸酐和己酸酐的甲醇溶液中被酰 化，通过核磁共振、元素分析、傅立叶红外光谱和X射线衍射表征其性质。通过性 能表征可知，壳聚糖的乙酰化反应比己酰化反应更快、更容易。另外，经乙酰化的 壳聚糖膜在降解过程中，降解速率比未改性和经己酰化的壳聚糖膜的降解速率快， 这与X射线衍射实验的实验结论是一致的，由X射线衍射实验得知，乙酰化壳聚糖 膜的结晶度较未改性和己酰化壳聚糖膜的结晶度低，所以更容易降解。虽然目前还 有许多问题尚待解决，距离工业化道路还有一定的距离，但是我们相信，随着科学 技术的不断发展，许多问题将在研究过程中得到解决，其应用前景将是十分广阔的。 关键词：壳聚糖，膜，酰化，改性 I 壳聚糖酰化膜的性能研究 Abstract Chitosan is the product of the chitin after the acylation reaction. It couldn’t dissolve in the water and alkaline solution. But it can dissolve in most of diluted acid can chitosan is linear high molecular polymer,the physicochemical properties is relative stability,and it can biodegrade. The viscosity and the property of forming fiber and forming film are excellent. Chitosan are used in chemical industry, pharmaceutical, foodstuff, fermentation and other domain widely. So it’s very necessary to study it. In this article , the major research is modified chitosan films. Chitosan films were acylated under heterogeneous conditions in methanol with acetic and hexanoic anhydrides and characterized by proton nuclear magnetic resonance, elemental analysis, and multiple internal reflective Fourier transform infrared spectroscopy. After the property characterization we can know acetylating reactions are more easily than hexanoylation reactions. In addition, biodegradation rate of the chitosan films after acetylating ar