脂肪酸类墙体保温相变储能材料的研究.pdfVIP

脂肪酸类墙体保温相变材料的研究 摘 要 研究了两组脂肪酸类相变材料的复配性质，选用的二元复配体系分别为硬脂 酸与十二酸，硬脂酸丁酯与硬脂酸乙酯。通过DSC检测不同组成复配物的相变焓， 温度变化，发现两组二元体系复配物的稳定性、可逆性均较好，相变焓较大。 将两组复配物的组成、相变温度作图，发现硬脂酸，十二酸最低共熔点的复 配物相变焓更大，相变温度在28℃左右，适合人体居住。因此，是理想的墙体保 温相变材料，可以用作内墙的保温材料。后者的最低共熔点在11℃左右，与人体 居住需要的的环境温度相比低，但相变焓大。因此，可以把该组复配物用作外墙 的保温材料。 关键词：脂肪酸类，墙体保温，相变材料, DSC I 脂肪酸类墙体保温相变材料的研究 The research of wall control temperature materials in the fatty acid phase change store energy Abstract the complex nature of two main fatty acids phase change materials was studied. The optional dual mixed systems are stearic acid and dodecoic acid, butyl stearate and ethyl stearate separately. With the help of DSC, the transformation of enthalpy and temperature which changes from different compositions are detected. As a result, the stability and the reversibility of these two complex binary systems are better, and more latent heat is released. After constructing the component and the phase transition temperature of these two groups composition, we found that the enthalpy of minimum melting point of stearic acid and dodecoic acid compound is greater, with the phase transition temperature around 28 ℃ . It is very suitable for human living. Therefore, it is choice for the phase change materials of insulated wall, as a thermal insulation material of interior walls. The lowest melting point of butyl stearate and ethyl stearate is about 11 ℃ , which is lower than human living environment temperature, but the enthalpy of phase change is large. Therefore, it is appropriate to put this compound phase change material into interior walls. Key words: fa