助剂 Co、Ni 对负载型氮化钼催化剂结构和吡啶加氢脱氮性能的影响.pdf

助剂 Co、Ni 对负载型氮化钼催化剂结构和吡啶加氢脱氮性能的影响 摘 要 本论文用浸渍法分别制备了Co含量为 2%、4%、6%、8%、Ni含量为 2%、4%、 6%、8%的负载型氮化钴钼、氮化镍钼催化剂。通过XRD、BET、NH -TPD等技术考 3 察了助剂对催化剂结构的影响；以吡啶为模型化合物，考察了Co、Ni含量对吡啶 加氢脱氮性能的影响。 XRD结果表明：助剂Co/Ni的加入可改善催化剂活性组分在载体表面的分散 性；从BET测定结果可以看出助剂的加入填充了催化剂的微孔，导致氮化钼催化 剂的比表面积下降。催化剂表面酸量测定证明了助剂Co对以γ-AlO 为载体的氮 2 3 化钼催化剂的表面酸性有一定的影响。通过考察所制备的催化剂上的吡啶加氢脱 氮反应，发现了Co、Ni的添加可以使Mo N/γ-Al O 催化剂上的吡啶加氢脱氮活性 2 2 3 增强。 关键词：助剂Co、Ni ，负载型氮化钼催化剂，吡啶加氢脱氮，影响 I 助剂 Co、Ni 对负载型氮化钼催化剂结构和吡啶加氢脱氮性能的影响 Abstract The supported CoMo （Co% ：2% 、4% 、6%、8% ）, NiMo （Ni% ：2% 、4% 、 6%、8% ）bimetallic nitrides catalysts were prepared by impregnation method and characterized by XRD, BET, NH -TPD. The influence of promoter Ni and Co was 3 tested by pyridine hydrodenitrogenation(HDN) in which pyridine was the model compound. The XRD results showed that the addition of promoter Co and Ni could enhance the disperse of the catalysts on support surface and could block up the micropore and reduce the BET surface area of the Mo N/γ-Al O catalysts. The addition of promoter 2 2 3 Co resulted in increasing of acid amount of the catalyst. The research of catalytic activities from pyridine HDN showed that the catalysts have higher HDN activity when Co or Ni was added. Key words: promoter Co and Ni ,supported Molybdenum nitrides catalysts, pyridine hydrodenitrogenation, influence