G级油井水泥水化过程中一界面的性能演化规律.docVIP

  G 级油井水泥水化过程中一界面的性能演 化规律# 任呈强，高雷，王煦，刘丽，郭小阳* 5 10 （西南石油大学材料科学与工程学院，成都 610500） 摘要：油井水泥与套管的界面被称为一界面，对油气井的完整性起到关键作用。采用交流阻 抗、界面剪切、显微硬度、微观形貌和物相分析技术研究了一界面在水化 1 天至 7 天的性能 演化规律。结果发现，电化学低频相位角和高频耗散角揭示水泥本体结构和界面结构逐渐达 到稳定；界面结合强度和过渡区显微硬度显著增加；界面过渡区的水化程度远落后于水泥本 体；该阶段界面过渡区的水化以 C2S 水化、残余 C3S 水化和 C3A 水化产物之间的反应为主， 对提高界面后期性能影响极大。升高养护压力有利于提高界面性能。 关键词：油井水泥；界面；电化学；力学性能；水化 中图分类号：TE256.7 15 Performance evolution of the first interface during hydration of class G oilwell cement REN Chengqiang, GAO Lei, WANG Xu, LIU Li, GUO Xiaoyang (School of Materials Science and Engineering, Southwest Petroleum University, Chengdu 610500, 20 25 30 35 40 China) Abstract: The interface between oilwell cement and casing is called as the first interface, which plays key role on the integrity of well. The methods of alternating current impedance, interfacial shearing, micro hardness, microstructure and phase analysis were adapted to investigated on the performance evolution of the first interface during hydration of class G oilwell cement from 1day to 7 days. The phase angle in low frequency range and loss angle in high frequency range by electrochemical tests discover the cement and the first interface gradually become stability. The bonding strength of interface and micro hardness of transition region increase markedly. The hydration degree of transition region is much slower than the cement. The process includes hydration reactions of C2S, residual C3S and products of C3A in the transition region, which influences the interfacial performance greatly. Higher pressure enhances the interfacial performance. Key words: oilwell cement, interface, electrochemistry, mechanical performance, hydration 0 引言 在油气工业中，固井水泥与套管的界面被称为第一界面（或一界面），水泥对套管起 到支撑和保护作用。 目前，油气井完整性受到国内外学者的高度重视，而固井水泥的长期封固性是保障油 气井完整性的关键之一[1,2]。当油井水泥返高固化后，与水泥本体比较而言，一界面相对是 一个较薄弱的区域。如果腐蚀性介质到达该界面，极易使界面失稳，从而形成气体和液体上 窜的通道，破坏油气井的完整性。William Carey 等[3]在分析服役 30 年的固井水泥时发现， 在套管/水泥界面附近有 0.1～0.3cm 厚的腐蚀产物析出区，推测 CO2 沿该界面发生了迁移， 破坏了界面的完整性。Barlet-Gouedard 等[4]调查指出，水