耐腐蚀的超疏水TiO2薄膜.docVIP

  A corrosion-resistance superhydrophobic TiO2 film# HU Yawei1,2, HUANG Siya1, LIU Shan1, PAN Wei1** (1. State Key Laboratory of New Ceramics and Fine Processing, Tsinghua University, 5 10 15 20 25 30 35 40 45 Beijing 100084; 2. College of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xi’an 710021) Abstract: A superhydrophobic TiO2 film with water contact angle greater than 170° on Hastelloy substrate was fabricated through simply dip-coating method from TiO2 precursor solution containing TiO2 nanoparticles with the average diameter 25 nm, followed by heat-treatment and modification with fluoroalkylsilane (FAS) molecules. The as-obtained sample was characterized by scanning electron microscopy (SEM), X-ray diffractometer (XRD), X-ray photoelectron spectroscopy (XPS), and water contact angle measurement respectively. Moreover, the dynamic light scattering (DLS) size distribution of TiO2 aggregated particles in the TiO2 prucursor solution containing P25 particles was evaluated by Laser Particle Sizer. It is found that the TiO2 nanoparticles in TiO2 precursor solution play a crucial role to form high superhydrophobicity. Simultaneously, the superhydrophobic TiO2 film still showed great superhydrophobicity after corroded with strong acid or alkali solutions and protected the substrate from corrosion which should be critical to the potential application in industry. Keywords: TiO2 film; superhydrophobicity; corrosion-resistance 0 Introduction Superhydrophobic surface with a water contact angle greater than 150° has aroused considerable interest in recent years because of the important applications in numerous aspects such as self-cleaning surfaces, non-contaminated materials, corrosion-resistant films, microfluidic devices, and other important industrial processes [1-4]. As is well known, superhydrophobicity of the solid surface is not only governed by the chemical composition but also by the geometrical microstructure of the surf