以直交表分析評估添加ROC 廢觸媒水泥漿體之性質.docVIP

以直交表分析評估添加ROC廢觸媒水泥漿體之性質* 魏良光1 ■許鎧麟2 ■張朝順3 * 九十八年十月二十二日在本會九十八年年會宣讀之論文 1國立高雄第一科技大學營建工程系 1工學院營建工程組博士生 2助理教授 3副教授 煉油工業之重油裂解製程（ROC）所產生的副產品廢觸媒，其主要化學成分為Al2O3及SiO2，具有部分非結晶相和波索蘭反應活性之特性。本文應用實驗設計法之直交表，對添加廢觸媒之水泥系複合材料的性質，進行系統性的分析與評估，以探討廢觸媒應用於水泥系營建材料之可行性。 本文以三種不同細度等級之廢觸媒粉，按不同比例取代水泥，添加於水泥複合材料中，並依據水泥漿體性質相關規範進行試驗，分析其活性指數與抗壓強度等特性，作為可行性研判之基準。亦即以廢觸媒粉細度與水泥取代比為實驗因子，進行二因子三水準直交表實驗設計，經特徵性質試驗後，藉由全距分析（Range Analysis）和變異數分析（Analysis of Variance），研析實驗因子與參數水準對試驗結果的影響趨勢與顯著性。 分析結果顯示：未經研磨處理之低細度廢觸媒粉，直接添加於水泥系複合材料中，活性指數介於102-125%之間、28天抗壓強度則介於418-508kgf/cm2間，均超過未添加廢觸媒粉之對照組；若以10-20%之比例取代水泥，相較於直接掩埋處理具有較高的經濟效益，其成本效益比最高可達7.4倍。本研究成果可作為爾後應用廢觸媒配比設計之依循參考，有效提昇廢觸媒粉再利用率，降低其廢棄處理對生態與環境的衝擊，達成資源永續利用之要求。 關鍵詞：水泥系複合材料、ROC、廢觸媒、直交表、全距分析、變異數分析 The residual product, waste catalyst powder produced in residual-oil-cracking (abbr. ROC) procedure, mainly composed of Al2O3 and SiO2, is featured of its partial non-crystalline phase and pozzolanic reaction. In this research, with the use of the orthogonal array in experiment design method, the properties of the cementitious material with the adding of the waste catalyst powder were systematically analyzed. And the research results can be used as the reference for evaluating the reuse feasibility of waste catalyst powder. What was carried out in this research is to replace cement by waste catalyst powder of 3 different fineness gardes in proportions by comparing the variation of the activity, compressive strength, etc. By introducing 2-factor-3-level orthogonal array for choosing the finencss-grade of powder and replace ratio of cement as expriment factors, the inf luence significancc of experiment factors and parameter levels could be judged with the help of range analysis and analysis of variance. The research results indicated that the low-finenessgrade waste catalyst powder without any processing could be added to cementitious materials directly. The activity was found around 102~125% and the compressive strength was between 415~508 kgf/cm2, When the cement replace ratio is 1