载体材料与贵金属催化剂.pdfVIP

载体材料与贵金属催化剂/金家敏等 ·45 · 载体材料与贵金属催化剂 金家敏，包伟芳，吴菊清，张德明 (上海材料研究所,上海 200437) 摘要 阐明电子循环授受催化机理的3 个基本论点，列举了多家实验结果作为佐证，指出Al O 、活性碳、碳黑等酸 2 3 性材料作为贵金属(Pt、Pd 等) 、金属(Fe、Ni 、Co 等)催化剂载体是不合理的。阐明了铁基催化剂氨合成反应、汽车尾气贵金 属净化催化反应、燃料电池铂催化反应等催化机理与碳气化催化反应机理是相同的。因此认为，从碳气化催化反应机理引出 的ECDAT 是多相催化反应机理的一个统一的基础理论。 关键词 催化 载体 贵金属 Supporter Materials and Noble Metal Catalyst JIN Jiaming ，BAO Weifang ，WU Qingju ，ZHANG Deming （Shanghai Research Institute of Materals，Shanghai 200437 ） Abstract In this paper, the basic principl of ECDAT have been explained and the experimental results from various authors have a brief introduction.It`s considered by the authors that the acidic materials such as Al O ,AC,carbon black etc.are a poisoner to 2 3 metal catalysts.If they are used as supporter metaials to metal catalysts such as Pt,Pd,Ru,Fe,Ni,Co etc.,which would result in much consumption of noble metals and energy. It is considered by the authors that the catalysis mechanism such as Fe-based ammonia synthesis catalytic reaction,automobile exhaust purification catalytic reaction,Pt catalytic reaction of fuel cell,Ru-based ammonia synthesis catalytic reaction etc. is the same as the catalysis mechanism of carbon gasification reaction.Therefore it is considered that the ECDAT is a basic theory for multiphase catalytic reaction. Keywords catalyze，carrier，noble metal 贵金属 Pt 等大量的被用作催化剂。用量最大的当推石 [1] 一文中 ，作者指出陶瓷材料载体有许多不足，其中最大的 油化工部门，其次是汽车催化剂。汽车尾气净化催化剂目前 不足是酸性的陶瓷材料有害贵金属催化剂活性，为了达到设 大量使用的是三效催化剂(有称三元催化剂) ，载体上涂Pt 、 计要求的转化率，必须用