铝合金专用无机防火涂料的制备.docVIP

论文 铝合金专用无机防火涂料的制备 赵艳红1，魏莉2 （1.沈阳理工大学应用技术学院，辽宁抚顺 113122；2.沈阳理工大学材料科学与工程学院，辽宁沈阳110168） 摘要：本文以无机阻燃原料为主要成分，添加适当的无机溶胶、助剂等，制备无机防火涂，于铝合金板上溶胶在Al/P为1：3.25溶胶的用量为%、添加剂粒度为1-2μm时，涂层表面均匀、致密、无缩孔。涂与基体材料在界面处有新相生成，且相互扩散形成过渡层，使涂与基体的结合强度得到提高。Preparation of Inorganic Fireproofing Paints Appropriate for Aluminum Alloy ZHAO Yanhong1, WEI Li2 (1 Polytechnic School, Shenyang Ligong University, Fushun, Liaoning, China 113000; 2 Faculty of Materials Science and Engineering, Shenyang Ligong University, Shenyang, Liaoning, China 110168) Abstract: In this paper, the preparation of inorganic fireproofing paints is discussed which is primarily consisted of inorganic non-combustible materials with suitable inorganic sol and agent on Al alloy plane for metro-interiors. It is studied the composition of the inorganic fireproofing paints and microcosmic structure on the interface of coating and Al alloy. The performance test about non-combustibility is carried out. The acid calcium phosphate is regarded primary compose, when the rate of Al/P is 1:3.25 and the amount of the adhesive agent is 60% and the granularity of the additive is 1~2μm, the surface of the coating is homogeneous, dense and no shrinking holes. A new phase is created on the interface of coating and basal materials, Coating and the substrate materials in the interface a new phase formation, and the spread between the formation of transition layer, so that the paint and the substrate bonding strength is improved. The fireproof of the coating can last for over 30min without combustion, scaling off, smoke and harmful gas and the coating materials possess good properties of fire proof and flaming retard. Keywords: inorganic fireproof coating, Al Alloy surface, inorganic sol, flaming retard 1引言 随着城市轨道交通的迅速发展，对地铁的防火要求越来越高。由于地铁系统的特殊性，使其在遭遇火灾时烟雾不易扩散，一些重大客车火灾事故都造成了重大的人员伤亡。事后调查表明，在火灾中丧生的人员中，大部分不是直接被烧死，而是被车厢内有机涂层和座椅等燃烧放出的毒烟熏死或熏晕后烧死的。 客车内饰防火涂层是一种集装饰、保护和防火一体的新型涂层，当它涂覆于基材上时，平时可起到一定的装饰、保护作用，一旦火灾发生时，则具有阻止火势蔓延的作用。目前轨道客车上的防火涂层多采用有机涂料，涂层遇火时能形成良好的具有隔热性能的致密