流态化分离洗涤对熟料高质量浓度溶出浆液二次反应的影响.docVIP

第 43 卷第 6 期 2012 年 6 月  中南大学学报(自然科学版) Journal of Central South University (Science and Technology)  Vol.43 No.6 June 2012  流态化分离洗涤对熟料高质量浓度溶出浆液二次反应的影响 彭志宏，陈彦虎，周秋生，刘桂华，李小斌，齐天贵 (中南大学冶金科学与工程学院，湖南长沙，410083) 摘要：采用流态化方式对烧结法熟料高质量浓度溶出浆液分离和赤泥洗涤进行研究。研究结果表明：对于 Al2O3 质量浓度为 240~270 g/L 的熟料溶出浆液，经流态化分离洗涤，可以同时实现浆液的固液分离和赤泥的洗涤，获 得的溢流(粗液)Al2O3 质量浓度为 170~190 g/L，底流液固质量比为 2.5~3.0，底流附液 Na2O 质量浓度为 6~9 g/L， 平均分离洗涤效率在 99%以上，平均二次反应损失为 0.16%；烧结法赤泥的流态化分离洗涤是抑制二次反应的有 效途径。 关键词：烧结法；浆液；流态化；分离；洗涤；二次反应 中图分类号：TF821 文献标志码：A 文章编号：1672?7207(2012)06?2036?07  Effect of fluidized separating-washing of red mud on secondary reactions of leached slurry with high alumina concentration PENG Zhi-hong, CHEN Yan-hu, ZHOU Qiu-sheng, LIU Gui-hua, LI Xiao-bin, QI Tian-gui (School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China) Abstract: The simultaneous separation and washing of red mud of the leached slurry with high alumina concentration in the sintering process was studied by employing the fluidization technique. The results show that the separation and washing of red mud can be achieved at the same time by fluidization method. When Al2O3 mass concentration of the leached slurry is 240?270 g/L, Na2O mass concentration of the underflow liquor and the liquid-solid mass ratio of the underflow can reach 6?9 g/L and 2.5?3.0, respectively, and Al2O3 mass concentration of the overflow is 170?190 g/L. The average efficiency of separating-washing is more than 99% with the average secondary reaction loss of 0.16%. It can be concluded that the fluidized separating-washing of red mud is an effective way to restrain secondary reactions. Key words: sintering process? slurry? fluidization? separation? washing? secondary reaction  在烧结法生产氧化铝的溶出赤泥分离和洗涤过程 中，由于熟料中存在原硅酸钙，不可避免地会发生二 次反应，并且随着液固接触时间的延长和溶液质量浓 [1] 赤泥分离与洗涤均采用沉降槽工艺，设备占地面积大， 投资大，分离洗涤时间长，二次反应损失大，造成碱 [2?3] 究能实现赤泥快速分离和洗涤的新的工艺。烧结法生 产的发展趋势是提高湿法