纳米二氧化钛电催化氧化工艺参数的研究.pdfVIP

纳米二氧化钛电催化氧化工艺参数的研究 刘占孟1 2 1 ，桑义敏 ，杨润昌 (1.湘潭大学环境工程系 2. 中国矿业大学(北京校区)) 摘要：采用吸附、焙烧法制备了纳米二氧化仗催化剂，用电催化系统对甲基橙溶液进行了电 催化氧化降解处理，考察了影响降解效果的主要因素。实验结果表明：电催化氧化降解效果随槽 电压的增加而提高，酸性条件更利于提高COD和色度的去除率，Fe2+浓度以及反应时间的增加同 样能提高降解效率。电催化氧化降解甲基橙的过程中，COD 的去除率低于色度的去除率。纳米 二氧化钛催化剂的催化效果显著，能够有效的去除甲基橙，去除机制主要是H O ，·OH对有机物 的氧化、降解。 2 2 rg 关键词：二氧化钛；甲基橙；电催化氧化；羟基自由基 o r. A Study of Parameters of Electrocatalytic Oxidation Process With Nanometer TiO2 e 1 2 1 LIU Zhan-meng , SANG Yi-min , YANG Run-chang t (1.Department of Environmeneal Engineering, Xiangtan University, Xiangtan 411105,China; a 2.China University of Mining Technology, Beijing 10083, China) w y Abstract ：A nanometer TiO2 catalyst was prepared by the method of adsorption-roasting ，a t degradation treatment of methyl orange solution was carried out in an electrocatalytic system by i 网 electrocatalytic oxidation, and the main factors affecting the resuh of the degradation were studied. It c was shown by the results of the test that the result of the degradation by electrocatalytic oxidation was a水 improving with the increasing of