水热法合成棒束状氧化铈及其催化性能的研究.docVIP

水热法合成棒束状及其催化性能 1,2，陈志刚1,2,3，马娟宁，钱君超1,2,3王盟盟（. 苏州科技学院化学生物工程学院，苏州 2150；. 苏州科技学院江苏省环境功能材料重点实验室，苏州 2150江苏大学材料科学与工程学院，镇江 212013） 摘要：在醇-水体系中以P123为模板硝酸铈和草酸为原料，利用水热法制备棒束状研究了反应温度、硝酸铈与草酸的摩尔比（M）、pH以及反应时间对颗粒的影响，确定了制备棒束状的最佳合成工艺结果表明：棒束状180℃、MCH=2:3、pH=1、t=360 min，对酸性品红催化活性普通块状CeO2更高。 关键词：催化性能；水热法；棒束状结构；氧化铈中国分类号O611.4 文献标识码 A 文章编号 Hydrothermal Synthesis of -like CeO2 Nano-powders and Its Catalytic Performance CHEN Feng1,2, CHEN Zhi-gang1,2,3*, MA Juan-ning3, QIAN Jun-chao 1,2,3, ZHANG Yu-zhu3, WANG Meng-meng3 (1. School of Chemistry, Biochemistry and Materials, Suzhou University of Science and Technology, Suzhou 215009; 2. Jiangsu Key Laboratory for Environment Functional Materials, Suzhou Univerisity of Science and Technology, Suzhou 215009; 3. Department of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013) Abstract: The cluster-like CeO2 nanopowders were prepared by the hydrothermal method in mixed alcohol-water solvents with Ce(NO3)3·6H2O and C2H2O4·2H2O as inorganic species and triblock copolymers P123 as template. The effect of hydrothermal reaction temperature, the ratio of cerium nitrate and oxalic acid (MCH), the pH of solution and reaction time were studied. The optimum condition of synthesis processing was indicated that hydrothermal reaction temperature was 200℃, MCH was 2:3, the pH of solution was 7 and reaction time was 360 min, and the catalytic performance of product could be investigated by the degradation of acid fuchsine. Compared to bulk CeO2, the cluster-like CeO2 nanopowder showed superior catalytic ability. Key words: Catalytic Performance; Hydrothermal Method; Cluster-like Structure; CeO2 0 引 言 是一种重要的稀土金属氧化物，因其独特的立方萤石结构Ce3+/Ce4+变换能力和氧化还原能力，而被广泛应用于固体氧化物燃料电池、汽车尾气催化、发光材料、电子陶瓷、气体传感器等。具有可控尺寸和形貌的纳米一直受到人们的密切关注近年来，研究人员合成了各种结构和形貌的，如纳米线[]、纳米片[]、纳米管[]、纳米立方体[]和纳米中空球[]等。目前，制备特殊形貌的方法主要有溶胶-凝胶法[]、模板法[]、静电纺丝技术[]和水热法[1]等。 水热法是指在密闭反应器中，采用水溶剂利用相对高温、高压的反应环境，使难溶或不溶的物质溶解重结晶进而无机材料的一种特殊方法[115]。铈离子价态应温度及反应时间对氧化铈的形貌有较大影响棱柱状氧化铈材料具有的氧缺陷，能有效提高其催化活性[1。水热法与传统的制